Acta Cryst. (2003). E59, m105-m107  [ doi:10.1107/S1600536803003507 ]

(³-Allyl)[(S)-(+)-(2-pyrrolidinylmethyl)pyrrolidine]palladium(II) trifluoromethanesulfonate

M. D. Jones, F. A. Almeida Paz, J. E. Davies and B. F. G. Johnson

Abstract: The title compound, [Pd(C₃H₅)(C₉H₁₈N₂)]CF₃SO₃, crystallizes in the non-centrosymmetric space group P2₁2₁2₁ and contains only one crystallographically unique Pd metal centre, showing a pseudo-square-planar geometry. (S)-(+)-(2-Pyrrolidinylmethyl)pyrrolidine (pmp, C₉H₁₈N₂) acts as an N,N'-bidentate chelating ligand, leading to the formation of the chiral [Pd(³-allyl)(pmp)]⁺ complex cation, which is hydrogen bonded to the trifluoromethanesulfonate anion.

Online 21 February 2003

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