Acta Cryst. (2003). E59, m108-m110  [ doi:10.1107/S1600536803003052 ]

Undecacarbonyl(₄-2-thiodithiobenzoato-⁴C,S,S',S'')(trimethylphosphite)tetrafer

E. A. Laifa, N. Benali-Cherif and H. Merazig

Abstract: The monosubstituted [Fe₄{P(OCH₃)₃}(C₇H₄S₃)(CO)₁₁] cluster is obtained by heating, at 328 K, the tetranuclear complex, TN [Fe₄(CO)₁₂(C₇H₄S₃)], with an excess of trimethylphosphite in acetone. The structure shows that P(OMe)₃ has replaced one carbonyl on the second Fe atom in the symmetric part of this tetranuclear cluster.

Copyright © International Union of Crystallography
IUCr Webmaster