Acta Cryst. (2003). E59, m192-m194  [ doi:10.1107/S1600536803005713 ]

Bis(triphenylphosphine)iminium -acetato-di--acetylacetonato-bis[acetylacetonatomagnesate(II)] monohydrate

P. G. Jones and M. M. Álvarez-Falcón

Abstract: In the title compound, (C₃₆H₃₀NP₂)[Mg₂(C₂H₃O₂)(C₅H₇O₂)₄]·H₂O, the anion involves two magnesium centres, one bridging acetate, two chelating acetylacetonates and two acetylacetonates each with one bridging and one non-bridging oxygen donor. The water molecule acts as an additional bridge via hydrogen bonds to two acetylacetonate O atoms.

Online 31 March 2003

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