![[HTML version]](/e/graphics/htmlborder.gif)
![[PDF version]](/e/graphics/pdfborder.gif)
![[CIF]](/e/graphics/cifborder.gif)
![[3d view]](/e/graphics/3dviewborder.gif)
![[Structure Factors]](/e/graphics/structurefactorsborder.gif)
![[CIF check Report]](/e/graphics/checkcifborder.gif)
![[Issue contents]](/e/graphics/issuecontentsborder.gif)
![[Buy article online]](/logos/buy.gif)
![[Contents scheme]](cf6246contents.gif)
Acta Cryst. (2003). E59, m207-m209 [ doi:10.1107/S1600536803006597 ]
![[triple bond]](/logos/entities/z-tbnd_rmgif.gif)
C bond of the alkynethiolate ligand in the cluster [Ru3(![[mu]](/logos/entities/mu_rmgif.gif)
3,![[eta]](/logos/entities/eta_rmgif.gif)
2-CCSiMe3)(-SCCSiMe3)(CO)9]Abstract: The structure of the title compound, 3,2-trimethylsilylethynyl--trimethylsilylethynethiolato-pentadecacarbonyldicobalttriruthenium, [Ru3Co2(3,2-CCSiMe3)(-SCCSiMe3)(CO)15], consists of an open triangular Ru3 framework with the acetylide ligand ![[sigma]](/logos/entities/sigma_rmgif.gif)
-bonded to one Ru atom and ![[pi]](/logos/entities/pi_rmgif.gif)
-bonded to the other two Ru atoms. Additionally, the SCCSiMe3 ligand, which has a Co2(CO)6 fragment coordinated to the CC bond, bridges the two terminal Ru atoms of the triangle to give a dimetallatetrahedrane structure.
Online 31 March 2003
Copyright © International Union of Crystallography
IUCr Webmaster