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Acta Cryst. (2003). E59, i72-i74  [ doi:10.1107/S1600536803006317 ]

Dipotassium bis[hexaaquacobalt(II)] decavanadate tetrahydrate

U. Lee, Y.-H. Jung and H.-C. Joo

Abstract: The title compound, K2[CoII(H2O)6]2[V10O28]·4H2O, was obtained by reacting CoCl2 with KVO3 and it was found to crystallize in the triclinic system in space group P\overline 1. The V...V distances are in the range 3.050  (1)-3.291  (2)  Å; the four types of V-O bond length are in the ranges 1.604  (3)-1.608  (3) (Ot), 1.902  (3)-2.006  (3) (Oc), 1.678  (3)-2.054  (3) (Ob) and 2.105  (3)-2.342  (3)  Å (Oh).

Online 23 April 2003


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