Acta Cryst. (2003). E59, m232-m233  [ doi:10.1107/S1600536803007244 ]

Bis[-methylenebis(diphenylphosphine)-²P:P']disilver(I) diperchlorate acetonitrile disolvate

Q. Wei, G. Yin and Z. Chen

Abstract: The dication in the title compound, [Ag₂(₂-dppm)₂](ClO₄)₂·2CH₃CN, where dppm is bis(diphenylphosphino)methane (C₂₅H₂₂P₂), is situated across an inversion centre. Each Ag atom is two-coordinate and exists in an approximately linear geometry. An AgN contact of 2.874  (10)  Å is observed in the structure.

Online 9 April 2003

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