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Acta Cryst. (2003). E59, m342-m344  [ doi:10.1107/S1600536803009838 ]

A one-dimensional double-wavelike chain coordination polymer: catena-poly[[diaquamanganese(II)]-[mu]-(2,2'-bipyridyl-3,3'-dicarboxylato-[kappa]4N,N':O,O')]

H.-T. Zhang, T. Shao, H.-Q. Wang and X.-Z. You

Abstract: The asymmetric unit of the title polymer, [Mn(C12H6N2O4)(H2O)2]n, consists of an MnII ion, which lies on a twofold axis, one half of a 2,2'-bipyridine-3,3'-dicarboxylate dianion and a coordinated water molecule. The one-dimensional chains extend into two-dimensional sheets via O-H...O hydrogen-bonding interactions. The crystal packing of the two-dimensional sheets appears to be dominated by aromatic [pi]-[pi] interactions.

Online 16 May 2003


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