Acta Cryst. (2003). E59, m317-m318  [ doi:10.1107/S1600536803009668 ]

Tris[-bis(diphenylphosphino)methane-²P:P']di-₃-sulfanido-trisilver(I) hexafluoroantimonate dichloromethane disolvate

Y.-H. Qin, M.-M. Wu and Z.-N. Chen

Abstract: The ₃-SH dicapped trisilver compound [Ag₃(-dppm)₃(₃-SH)₂]SbF₆·2CH₂Cl₂ [dppm is bis(diphenylphosphino)methane, C₂₅H₂₂P₂], formed by the reaction between [Ag₂(-dppm)₂(MeCN)₂](SbF₆)₂ and [Pd(phen)(tdt)] (phen is o-phenanthroline and tdt is toluene-3,4-dithiolate) through the disruption of C-S bonds, exhibits a trigonal bipyramid core, with two ₃-SH ligands at the apices. The Ag atoms are located in tetrahedral environments with P₂S₂ donors.

Online 9 May 2003

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