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Acta Cryst. (2003). E59, m310-m312 [ doi:10.1107/S1600536803009383 ]
-Aqua-S-citrato(2-)manganese(II)Abstract: The citrato(2-) ligand in aquacitrato(2-)manganese(II), [Mn(C6H6O7)(H2O)], chelates the Mn atom through the
-hydroxyl, the
-carboxyl and one
-carboxyl O atom, while the other
-carboxylic acid group remains uncoordinated. Each O atom of the
-carboxyl groups is bonded to an adjacent Mn atom, leading to octahedral Mn and a helical chain. Neighboring chains are consolidated into a tightly held crystal structure by hydrogen bonds.
Online 9 May 2003
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