[HTML version][PDF version][CIF][3d view][Structure Factors][CIF check Report][Issue contents]  [Buy article online]

[Contents scheme]

Acta Cryst. (2003). E59, m348-m349  [ doi:10.1107/S1600536803010420 ]

Bis(N-cyclohexyl-N-methyldithiocarbamato)dimethyltin(IV)

N. Awang, I. Baba, M. S. M. Yusof and B. M. Yamin

Abstract: The molecule of the title compound, [Sn(CH3)2(C8H14NS2)2], occupies a special position on a crystallographic mirror plane which coincides with the plane of the dimethyltin group. The severely distorted coordination tetrahedron formed by the four strong bonds of the Sn atom [Sn-C = 2.101  (4) and 2.108  (5)  Å, Sn-S = 2.5169  (7)  Å, C-Sn-C = 137.0  (2)° and S-Sn-S = 84.46  (3)°] is expanded to a distorted octahedron due to weak intramolecular Sn...S interactions of 2.9785  (6)  Å.

Online 16 May 2003


Copyright © International Union of Crystallography
IUCr Webmaster