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Acta Cryst. (2003). E59, m536-m537  [ doi:10.1107/S1600536803013813 ]

[mu]-1,4-Bis(diphenylphosphino)butane-[kappa]2P:P'-bis[(2,2'-bipyridyl)silver(I)] ditetrafluoroborate

L. Zhang, C.-L. Chen, Q. Zhang, H.-X. Zhang and B.-S. Kang

Abstract: Pink crystals of the title dinuclear complex, [Ag2(C10H8N2)2(C28H28P2)](BF4)2, were obtained from a methanol solution of equivalent amounts of AgBF4, 2,2'-bipyridyl (bipy) and 1,4-bis(diphenylphosphino)butane (dppb). The [Ag2(bipy)2(dppb)]2+ cation lies across a crystallographic inversion centre and the coordination environment around AgI is distorted trigonal.

Online 30 June 2003


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