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Acta Cryst. (2003). E59, m538-m540  [ doi:10.1107/S1600536803012741 ]

([eta]3-Allyl)[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]palladium(II) trifluoromethanesulfonate dichloromethane solvate

M. D. Jones, F. A. Almeida Paz, J. E. Davies, B. F. G. Johnson and J. Klinowski

Abstract: The crystal structure of the title compound, [Pd(C3H5)(C44H32P2)](CF3SO3)·CH2Cl2, has been determined at 180  (2)  K in the non-centrosymmetric space group P212121. The structure contains only one crystallographically unique Pd metal centre, exhibiting a pseudo-square-planar geometry, and is formed by cationic layers intercalated by trifluoromethanesulfonate anions and dichloromethane molecules.

Online 30 June 2003


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