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Acta Cryst. (2003). E59, m470-m472  [ doi:10.1107/S1600536803012819 ]

Diaqua(2,6-dioxo-1,2,3,6-tetrahydropyrimidine-4-carboxylato-[kappa]N3)(1,10-phenanthroline)zinc(II) dihydrate

X. Li, W. Bi, D. Yuan and R. Cao

Abstract: In the title compound, [Zn(C5H2N2O4)(C12H8N2)(H2O)2]·2H2O, the Zn atom is coordinated by N and O atoms from the orotate (2,6-dioxo-1,2,3,6-tetrahydropyrimidine-4-carboxylate) ligand, two N atoms from 1,10-phenanthroline and two aqua O atoms in a distorted octahedral geometry. The presence of intermolecular N-H...O and O-H...O hydrogen bonds and [pi]-[pi]-stacking interactions between the phenanthroline ligands results in a three-dimensional structure.

Online 17 June 2003


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