Acta Cryst. (2003). E59, m633-m635  [ doi:10.1107/S1600536803015691 ]

(Acetylacetonato)carbonyl[diallyl(tert-butyl)phosphine]rhodium(I)

E. Ocando-Mavarez, J. Ascanio, T. González, R. Atencio, M. Rosales and N. Silva

Abstract: The crystal structure of the title compound, [Rh(C₅H₇O₂)(C₁₀H₁₉P)(CO)], consists of discrete chiral molecules. The square-planar coordination geometry around Rh^I involves two O atoms of one acetylacetonate ligand, one carbonyl group and one P atom of a monodentate diallylphosphine. The double bonds of the allyl groups have a mutual - interaction.

Online 24 July 2003

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