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Acta Cryst. (2003). E59, m669-m670  [ doi:10.1107/S1600536803016222 ]

([eta]6-Benzene)bis([eta]6-p-cymene)tri-[mu]-hydrido-[mu]3-oxo-triruthenium hexafluorophosphate

L. Vieille-Petit, B. Therrien and G. Süss-Fink

Abstract: The trinuclear arene-ruthenium cluster cation [H3Ru3([eta]6-C6H6)([eta]6-C6H4MePri-p)2([mu]3-O)]+has been synthesized and crystallized as the hexafluorophosphate salt. The cation possesses a mirror plane through the ([eta]6-benzene)ruthenium moiety and the [mu]3-O atom, and is disordered over a perpendicular mirror plane that includes the three Ru atoms.

Online 31 July 2003


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