Binuclear trans-μ-pyrazine-bis­[bromo­tetra­pyridine­ruthenium(II)] dihexa­fluoro­phosphate di­methyl­form­amide disolvate

The Ru atoms of the title compound, [Ru₂Br₂(C₄H₄N₂)(C₅H₅N)₈](PF₆)₂.2C₃H₇NO, are coordinated by the four N atoms of the pyridine (py) ligands and a bromide. Two such units are bridged by a pyrazine (pz) unit, which is disposed about a centre of inversion, so as to form a trans pseudo-octahedral geometry about Ru. The py units are in an eclipsed conformation when viewed down the internuclear axis. The Ru—N(pz) distance is 2.079 (3) Å, while the Ru—Br distance is 2.5524 (4) Å.

Key indicators

• Single-crystal X-ray study
• T = 293 K
• Mean [sigma](C-C) = 0.006 Å
Some non-H atoms missing
• Disorder in solvent or counterion
• R factor = 0.042
• wR factor = 0.115
• Data-to-parameter ratio = 19.8

checkCIF results

No syntax errors found

ADDSYM reports no extra symmetry


 Alert Level A:



PLAT_601  Alert A Structure Contains Solvent Accessible VOIDS of .     252.00 A   3

Author response: During the structure refinement, the atoms of the DMF solvent molecule were observed but could not be modelled satisfactorily. The SQUEEZE routine in PLATON was used to modify the HKL file and the solvent equated to one molecule of DMF, per molecule of complex.

 Alert Level C:



PLAT_302  Alert C Anion/Solvent Disorder .........................      36.00 Perc.

General Notes



FORMU_01  There is a discrepancy between the atom counts in the
          _chemical_formula_sum and the formula from the _atom_site* data.
          Atom count from _chemical_formula_sum:C50 H58 Br2 F12 N12 O2 P2 Ru2
          Atom count from the _atom_site data:  C44 H44 Br2 F12 N10 P2 Ru2

CELLZ_01
         From the CIF: _cell_formula_units_Z    4
         From the CIF: _chemical_formula_sum  C50 H58 Br2 F12 N12 O2 P2 Ru2
         TEST: Compare cell contents of formula and atom_site data

         atom    Z*formula  cif sites diff
         C        200.00    176.00   24.00
         H        232.00    176.00   56.00
         Br         8.00      8.00    0.00
         F         48.00     48.00    0.00
         N         48.00     40.00    8.00
         O          8.00      0.00    8.00
         P          8.00      8.00    0.00
         Ru         8.00      8.00    0.00
          Difference between formula and atom_site contents detected.
          ALERT: Large difference may be due to a
          symmetry error - see SYMMG tests

CHEMW_03
         From the CIF: _cell_formula_units_Z                    4
         From the CIF: _chemical_formula_weight          1510.98
         TEST: Calculate formula weight from _atom_site_*
         atom     mass    num     sum
         C        12.01   44.00  528.48
         H         1.01   44.00   44.35
         N        14.01   10.00  140.07
         O        16.00    0.00    0.00
         F        19.00   12.00  227.98
         P        30.97    2.00   61.95
         Br       79.90    2.00  159.81
         Ru      101.07    2.00  202.14
         Calculated formula weight             1364.78
          ALERT: The ratio of given/expected molecular weight as calculated
          from the _atom_site* data lies outside
          the range 0.90 <> 1.10


 1 Alert Level A = Potentially serious problem

 0 Alert Level B = Potential problem

 1 Alert Level C = Please check

---

Computing details

Data collection: COLLECT (Nonius, 1997-2001); cell refinement: DENZO-SMN (Otwinowski & Minor, 1997); data reduction: DENZO-SMN; program(s) used to solve structure: SHELXS97 (Sheldrick, 1990); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL (Sheldrick 1999); software used to prepare material for publication: SHELXTL.

(I)

Crystal data

[Ru2Br2(C4H4N2)(C5H5N)8](PF6)2·2C3H7NO	F(000) = 3016
Mr = 1510.98	Dx = 1.695 Mg m^−3
Monoclinic, C2/c	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -C 2yc	Cell parameters from 42564 reflections
a = 19.0401 (4) Å	θ = 2.6–27.5°
b = 14.6334 (4) Å	µ = 2.00 mm^−1
c = 21.2490 (5) Å	T = 293 K
β = 90.5609 (12)°	Prism, dark red
V = 5920.1 (2) Å^3	0.18 × 0.10 × 0.02 mm
Z = 4

Data collection

Nonius KappaCCD diffractometer	6741 independent reflections
Radiation source: fine-focus sealed tube	5561 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.046
φ scans, and ω scans with κ offsets	θmax = 27.5°, θmin = 2.9°
Absorption correction: multi-scan (DENZO-SMN; Otwinowski & Minor, 1997)	h = −24→24
Tmin = 0.715, Tmax = 0.961	k = −18→18
21516 measured reflections	l = −27→27

Refinement

Refinement on F^2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F^2 > 2σ(F^2)] = 0.042	Hydrogen site location: inferred from neighbouring sites
wR(F^2) = 0.115	H-atom parameters constrained
S = 1.07	w = 1/[σ^2(Fo^2) + (0.0569P)^2 + 4.3116P] where P = (Fo^2 + 2Fc^2)/3
6741 reflections	(Δ/σ)max = 0.001
341 parameters	Δρmax = 0.48 e Å^−3
4 restraints	Δρmin = −0.90 e Å^−3

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Some highly disordered solvent peaks of DMF molecule were observed but could not be modelled satisfactorily. The SQUEEZE routine in PLATON was used to modify the HKL file and the solvent equated to one molecule of dimethylformamide, per molecule of complex.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq	Occ. (<1)
Br1	0.323952 (19)	0.36001 (3)	0.266899 (16)	0.03966 (11)
Ru1	0.294415 (12)	0.314466 (18)	0.153748 (12)	0.02643 (9)
P1	−0.00851 (5)	0.28739 (7)	0.05085 (5)	0.0403 (2)
F1A	0.01396 (18)	0.2068 (2)	0.0051 (2)	0.0811 (11)	0.91
F2A	0.04451 (16)	0.2475 (3)	0.10225 (18)	0.0836 (12)	0.91
F3A	−0.03014 (19)	0.3654 (2)	0.09742 (18)	0.0781 (10)	0.91
F4A	−0.06082 (16)	0.3261 (3)	−0.00082 (18)	0.0843 (12)	0.91
F1B	−0.0229 (19)	0.255 (3)	−0.0198 (7)	0.069 (8)*	0.09
F2B	0.0471 (10)	0.2075 (13)	0.0574 (14)	0.042 (5)*	0.09
F3B	0.0214 (19)	0.321 (3)	0.1174 (9)	0.070 (9)*	0.09
F4B	−0.0550 (13)	0.3781 (13)	0.0442 (16)	0.056 (7)*	0.09
F5	0.05360 (12)	0.34935 (17)	0.02347 (12)	0.0518 (6)
F6	−0.06946 (13)	0.2253 (2)	0.07838 (15)	0.0644 (7)
N1	0.20645 (14)	0.2482 (2)	0.19077 (13)	0.0324 (6)
N2	0.35535 (14)	0.19496 (19)	0.16546 (14)	0.0320 (6)
N3	0.38489 (14)	0.3855 (2)	0.12560 (13)	0.0307 (6)
N4	0.23714 (14)	0.43628 (19)	0.14201 (13)	0.0307 (6)
N5	0.26864 (13)	0.27619 (18)	0.06217 (12)	0.0269 (5)
C1	0.16471 (18)	0.2920 (3)	0.23229 (17)	0.0384 (8)
H1	0.1729	0.3550	0.2402	0.046*
C2	0.1102 (2)	0.2485 (4)	0.2643 (2)	0.0524 (11)
H2	0.0819	0.2813	0.2931	0.063*
C3	0.0983 (2)	0.1575 (4)	0.2534 (2)	0.0574 (13)
H3	0.0626	0.1258	0.2754	0.069*
C4	0.1388 (2)	0.1127 (3)	0.2099 (2)	0.0515 (11)
H4	0.1303	0.0501	0.2008	0.062*
C5	0.19202 (19)	0.1592 (3)	0.17967 (19)	0.0394 (8)
H5	0.2194	0.1272	0.1498	0.047*
C6	0.35035 (19)	0.1445 (3)	0.21843 (19)	0.0392 (8)
H6	0.3194	0.1642	0.2505	0.047*
C7	0.3889 (2)	0.0650 (3)	0.2278 (2)	0.0506 (10)
H7	0.3840	0.0311	0.2656	0.061*
C8	0.4340 (3)	0.0360 (3)	0.1823 (2)	0.0590 (12)
H8	0.4602	−0.0188	0.1876	0.071*
C9	0.4405 (2)	0.0874 (3)	0.1286 (2)	0.0551 (11)
H9	0.4719	0.0694	0.0964	0.066*
C10	0.4009 (2)	0.1660 (3)	0.12217 (19)	0.0426 (9)
H10	0.4062	0.2013	0.0850	0.051*
C11	0.44568 (17)	0.3750 (3)	0.15845 (17)	0.0372 (8)
H11	0.4482	0.3290	0.1899	0.045*
C12	0.50432 (18)	0.4289 (3)	0.1481 (2)	0.0448 (9)
H12	0.5460	0.4196	0.1721	0.054*
C13	0.50156 (19)	0.4958 (3)	0.10305 (19)	0.0442 (9)
H13	0.5406	0.5348	0.0962	0.053*
C14	0.44085 (19)	0.5053 (3)	0.06793 (18)	0.0399 (8)
H14	0.4383	0.5499	0.0355	0.048*
C15	0.38409 (17)	0.4498 (2)	0.07970 (15)	0.0324 (7)
H15	0.3428	0.4572	0.0548	0.039*
C16	0.26637 (18)	0.5171 (2)	0.15867 (16)	0.0345 (7)
H16	0.3096	0.5165	0.1814	0.041*
C17	0.2364 (2)	0.6003 (3)	0.1442 (2)	0.0458 (9)
H17	0.2588	0.6555	0.1567	0.055*
C18	0.1732 (2)	0.6028 (3)	0.1110 (2)	0.0536 (10)
H18	0.1522	0.6593	0.0994	0.064*
C19	0.1419 (2)	0.5212 (3)	0.0958 (2)	0.0469 (9)
H19	0.0978	0.5205	0.0743	0.056*
C20	0.17450 (18)	0.4406 (3)	0.11142 (17)	0.0357 (7)
H20	0.1520	0.3849	0.1002	0.043*
C21	0.20344 (16)	0.2471 (2)	0.04590 (15)	0.0287 (6)
H21	0.1685	0.2444	0.0774	0.034*
C22	0.18596 (16)	0.2217 (2)	−0.01457 (16)	0.0298 (6)
H22	0.1394	0.2014	−0.0229	0.036*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Br1	0.0421 (2)	0.0472 (2)	0.02950 (19)	−0.00843 (15)	−0.00730 (15)	−0.00066 (15)
Ru1	0.02395 (14)	0.02955 (15)	0.02571 (15)	−0.00255 (9)	−0.00417 (10)	0.00040 (10)
P1	0.0318 (4)	0.0449 (6)	0.0442 (5)	0.0007 (4)	0.0019 (4)	−0.0018 (4)
F1A	0.069 (2)	0.063 (2)	0.112 (3)	−0.0135 (17)	0.042 (2)	−0.032 (2)
F2A	0.0494 (16)	0.123 (3)	0.079 (2)	0.0046 (19)	−0.0102 (16)	0.044 (2)
F3A	0.084 (2)	0.066 (2)	0.085 (2)	−0.0133 (17)	0.034 (2)	−0.0324 (18)
F4A	0.0462 (16)	0.132 (3)	0.075 (2)	−0.0038 (19)	−0.0168 (16)	0.038 (2)
F5	0.0422 (12)	0.0551 (15)	0.0582 (15)	−0.0093 (11)	0.0046 (11)	0.0005 (12)
F6	0.0452 (13)	0.0613 (16)	0.087 (2)	−0.0041 (12)	0.0202 (13)	0.0031 (15)
N1	0.0287 (13)	0.0381 (16)	0.0303 (14)	−0.0024 (12)	−0.0044 (11)	0.0027 (12)
N2	0.0292 (13)	0.0336 (15)	0.0331 (15)	−0.0002 (11)	−0.0048 (12)	0.0031 (12)
N3	0.0267 (12)	0.0355 (15)	0.0299 (14)	−0.0022 (11)	−0.0043 (11)	−0.0001 (12)
N4	0.0296 (13)	0.0319 (15)	0.0305 (14)	−0.0020 (11)	−0.0034 (11)	−0.0033 (11)
N5	0.0253 (12)	0.0268 (13)	0.0285 (13)	0.0022 (10)	−0.0014 (10)	0.0011 (11)
C1	0.0326 (16)	0.051 (2)	0.0313 (17)	−0.0002 (15)	0.0014 (14)	0.0029 (15)
C2	0.0323 (18)	0.083 (3)	0.043 (2)	0.002 (2)	0.0041 (16)	0.016 (2)
C3	0.0309 (19)	0.076 (3)	0.065 (3)	−0.013 (2)	−0.0075 (19)	0.034 (3)
C4	0.041 (2)	0.049 (2)	0.064 (3)	−0.0176 (18)	−0.023 (2)	0.021 (2)
C5	0.0360 (18)	0.0370 (19)	0.045 (2)	−0.0071 (15)	−0.0128 (16)	0.0106 (16)
C6	0.0371 (18)	0.041 (2)	0.040 (2)	0.0030 (15)	−0.0034 (15)	0.0060 (16)
C7	0.057 (2)	0.047 (2)	0.048 (2)	0.0108 (19)	−0.0066 (19)	0.0144 (19)
C8	0.064 (3)	0.051 (3)	0.062 (3)	0.024 (2)	−0.006 (2)	0.008 (2)
C9	0.051 (2)	0.061 (3)	0.053 (3)	0.023 (2)	−0.003 (2)	0.000 (2)
C10	0.0383 (19)	0.047 (2)	0.042 (2)	0.0066 (16)	−0.0030 (16)	0.0036 (17)
C11	0.0294 (16)	0.046 (2)	0.0360 (18)	−0.0071 (14)	−0.0069 (14)	0.0035 (16)
C12	0.0286 (16)	0.058 (2)	0.048 (2)	−0.0094 (16)	−0.0098 (16)	0.0005 (19)
C13	0.0329 (17)	0.053 (2)	0.047 (2)	−0.0130 (17)	−0.0008 (16)	0.0040 (18)
C14	0.0393 (18)	0.044 (2)	0.0365 (18)	−0.0083 (16)	−0.0002 (15)	0.0037 (16)
C15	0.0312 (15)	0.0376 (18)	0.0285 (16)	−0.0045 (14)	−0.0030 (13)	0.0010 (14)
C16	0.0374 (17)	0.0328 (18)	0.0332 (17)	−0.0035 (14)	−0.0006 (14)	−0.0044 (14)
C17	0.053 (2)	0.035 (2)	0.049 (2)	−0.0008 (17)	−0.0005 (18)	−0.0007 (17)
C18	0.058 (2)	0.042 (2)	0.061 (3)	0.0122 (19)	−0.007 (2)	0.005 (2)
C19	0.046 (2)	0.049 (2)	0.046 (2)	0.0112 (18)	−0.0099 (18)	−0.0061 (18)
C20	0.0345 (16)	0.0360 (18)	0.0364 (18)	0.0024 (14)	−0.0081 (14)	−0.0048 (15)
C21	0.0253 (14)	0.0303 (17)	0.0304 (16)	−0.0018 (12)	−0.0010 (12)	−0.0024 (13)
C22	0.0245 (14)	0.0319 (16)	0.0328 (16)	−0.0025 (12)	−0.0027 (12)	0.0001 (14)

Geometric parameters (Å, º)

Ru1—Br1	2.5524 (4)	C4—H4	0.9499
Ru1—N1	2.095 (3)	C5—H5	0.9500
Ru1—N2	2.112 (3)	C6—C7	1.389 (5)
Ru1—N3	2.103 (3)	C6—H6	0.9501
Ru1—N4	2.103 (3)	C7—C8	1.367 (7)
Ru1—N5	2.079 (3)	C7—H7	0.9499
P1—F1A	1.591 (3)	C8—C9	1.373 (7)
P1—F2A	1.591 (3)	C8—H8	0.9500
P1—F3A	1.569 (3)	C9—C10	1.381 (6)
P1—F4A	1.580 (3)	C9—H9	0.9500
P1—F1B	1.595 (10)	C10—H10	0.9500
P1—F2B	1.582 (10)	C11—C12	1.386 (5)
P1—F3B	1.597 (10)	C11—H11	0.9500
P1—F4B	1.601 (10)	C12—C13	1.370 (6)
P1—F5	1.604 (2)	C12—H12	0.9501
P1—F6	1.590 (3)	C13—C14	1.377 (5)
N1—C5	1.351 (5)	C13—H13	0.9502
N1—C1	1.354 (5)	C14—C15	1.376 (5)
N2—C10	1.339 (5)	C14—H14	0.9499
N2—C6	1.350 (5)	C15—H15	0.9500
N3—C11	1.354 (4)	C16—C17	1.379 (5)
N3—C15	1.356 (4)	C16—H16	0.9500
N4—C16	1.353 (4)	C17—C18	1.389 (6)
N4—C20	1.354 (4)	C17—H17	0.9500
N5—C22^i	1.337 (4)	C18—C19	1.372 (6)
N5—C21	1.354 (4)	C18—H18	0.9499
C1—C2	1.400 (5)	C19—C20	1.374 (5)
C1—H1	0.9500	C19—H19	0.9500
C2—C3	1.370 (7)	C20—H20	0.9499
C2—H2	0.9499	C21—C22	1.375 (5)
C3—C4	1.376 (7)	C21—H21	0.9500
C3—H3	0.9501	C22—N5^i	1.337 (4)
C4—C5	1.384 (5)	C22—H22	0.9499
N1—Ru1—N2	90.73 (11)	C3—C2—H2	120.5
N1—Ru1—N3	174.38 (11)	C1—C2—H2	120.7
N1—Ru1—N4	91.22 (11)	C2—C3—C4	118.9 (4)
N1—Ru1—N5	92.55 (10)	C2—C3—H3	120.6
N2—Ru1—N3	89.54 (11)	C4—C3—H3	120.5
N2—Ru1—N4	177.91 (10)	C3—C4—C5	119.7 (4)
N2—Ru1—N5	90.66 (11)	C3—C4—H4	120.0
N3—Ru1—N4	88.44 (11)	C5—C4—H4	120.3
N3—Ru1—N5	93.06 (10)	N1—C5—C4	122.8 (4)
N4—Ru1—N5	90.00 (10)	N1—C5—H5	118.7
N1—Ru1—Br1	86.38 (8)	C4—C5—H5	118.5
N2—Ru1—Br1	89.40 (8)	N2—C6—C7	122.4 (4)
N3—Ru1—Br1	88.02 (8)	N2—C6—H6	118.8
N4—Ru1—Br1	89.98 (8)	C7—C6—H6	118.8
N5—Ru1—Br1	178.92 (7)	C8—C7—C6	119.6 (4)
F3A—P1—F4A	90.6 (2)	C8—C7—H7	120.3
F3A—P1—F6	89.27 (16)	C6—C7—H7	120.1
F4A—P1—F6	90.18 (17)	C7—C8—C9	118.6 (4)
F2B—P1—F6	92.0 (9)	C7—C8—H8	120.7
F3A—P1—F1A	178.6 (3)	C9—C8—H8	120.7
F4A—P1—F1A	90.7 (2)	C8—C9—C10	119.1 (4)
F6—P1—F1A	90.15 (16)	C8—C9—H9	120.5
F3A—P1—F2A	90.1 (2)	C10—C9—H9	120.5
F4A—P1—F2A	179.3 (3)	N2—C10—C9	123.5 (4)
F6—P1—F2A	89.91 (17)	N2—C10—H10	118.3
F1A—P1—F2A	88.6 (3)	C9—C10—H10	118.2
F2B—P1—F1B	88.4 (18)	N3—C11—C12	122.7 (3)
F6—P1—F1B	93.3 (12)	N3—C11—H11	118.6
F2B—P1—F3B	85.2 (18)	C12—C11—H11	118.7
F6—P1—F3B	96.0 (13)	C13—C12—C11	119.4 (3)
F1B—P1—F3B	168.9 (19)	C13—C12—H12	120.3
F2B—P1—F4B	171.5 (14)	C11—C12—H12	120.3
F6—P1—F4B	95.9 (10)	C12—C13—C14	118.5 (3)
F1B—P1—F4B	94.2 (19)	C12—C13—H13	120.8
F3B—P1—F4B	90.9 (19)	C14—C13—H13	120.7
F3A—P1—F5	90.93 (16)	C13—C14—C15	119.9 (4)
F4A—P1—F5	90.43 (16)	C13—C14—H14	120.0
F2B—P1—F5	87.4 (9)	C15—C14—H14	120.1
F6—P1—F5	179.36 (17)	N3—C15—C14	122.5 (3)
F1A—P1—F5	89.64 (15)	N3—C15—H15	118.9
F2A—P1—F5	89.48 (16)	C14—C15—H15	118.7
F1B—P1—F5	87.0 (12)	N4—C16—C17	123.1 (3)
F3B—P1—F5	83.7 (13)	N4—C16—H16	118.4
F4B—P1—F5	84.7 (10)	C17—C16—H16	118.5
C5—N1—C1	116.7 (3)	C16—C17—C18	119.3 (4)
C5—N1—Ru1	122.8 (2)	C16—C17—H17	120.4
C1—N1—Ru1	120.1 (2)	C18—C17—H17	120.3
C10—N2—C6	116.8 (3)	C19—C18—C17	118.1 (4)
C10—N2—Ru1	122.7 (2)	C19—C18—H18	121.0
C6—N2—Ru1	120.5 (2)	C17—C18—H18	120.9
C11—N3—C15	116.9 (3)	C20—C19—C18	119.7 (4)
C11—N3—Ru1	119.7 (2)	C20—C19—H19	120.1
C15—N3—Ru1	123.0 (2)	C18—C19—H19	120.2
C16—N4—C20	116.3 (3)	N4—C20—C19	123.4 (3)
C16—N4—Ru1	119.9 (2)	N4—C20—H20	118.3
C20—N4—Ru1	123.3 (2)	C19—C20—H20	118.3
C22^i—N5—C21	114.3 (3)	N5—C21—C22	122.5 (3)
C22^i—N5—Ru1	123.6 (2)	N5—C21—H21	118.7
C21—N5—Ru1	122.1 (2)	C22—C21—H21	118.8
N1—C1—C2	123.0 (4)	N5^i—C22—C21	123.2 (3)
N1—C1—H1	118.6	N5^i—C22—H22	118.3
C2—C1—H1	118.5	C21—C22—H22	118.4
C3—C2—C1	118.8 (4)
N5—Ru1—N1—C5	54.0 (3)	N3—Ru1—N5—C21	−162.2 (3)
N4—Ru1—N1—C5	144.1 (3)	N2—Ru1—N5—C21	108.2 (3)
N2—Ru1—N1—C5	−36.7 (3)	C5—N1—C1—C2	1.8 (5)
Br1—Ru1—N1—C5	−126.0 (3)	Ru1—N1—C1—C2	−172.3 (3)
N5—Ru1—N1—C1	−132.2 (3)	N1—C1—C2—C3	0.1 (6)
N4—Ru1—N1—C1	−42.1 (3)	C1—C2—C3—C4	−2.0 (6)
N2—Ru1—N1—C1	137.1 (3)	C2—C3—C4—C5	2.0 (6)
Br1—Ru1—N1—C1	47.8 (2)	C1—N1—C5—C4	−1.8 (5)
N5—Ru1—N2—C10	45.9 (3)	Ru1—N1—C5—C4	172.1 (3)
N1—Ru1—N2—C10	138.5 (3)	C3—C4—C5—N1	0.0 (6)
N3—Ru1—N2—C10	−47.2 (3)	C10—N2—C6—C7	−1.6 (5)
Br1—Ru1—N2—C10	−135.2 (3)	Ru1—N2—C6—C7	179.3 (3)
N5—Ru1—N2—C6	−135.0 (3)	N2—C6—C7—C8	0.4 (6)
N1—Ru1—N2—C6	−42.4 (3)	C6—C7—C8—C9	0.6 (7)
N3—Ru1—N2—C6	131.9 (3)	C7—C8—C9—C10	−0.4 (7)
Br1—Ru1—N2—C6	43.9 (3)	C6—N2—C10—C9	1.8 (6)
N5—Ru1—N3—C11	−135.5 (3)	Ru1—N2—C10—C9	−179.1 (3)
N4—Ru1—N3—C11	134.6 (3)	C8—C9—C10—N2	−0.9 (7)
N2—Ru1—N3—C11	−44.8 (3)	C15—N3—C11—C12	2.3 (5)
Br1—Ru1—N3—C11	44.6 (3)	Ru1—N3—C11—C12	−170.7 (3)
N5—Ru1—N3—C15	52.0 (3)	N3—C11—C12—C13	0.0 (6)
N4—Ru1—N3—C15	−37.9 (3)	C11—C12—C13—C14	−2.0 (6)
N2—Ru1—N3—C15	142.6 (3)	C12—C13—C14—C15	1.7 (6)
Br1—Ru1—N3—C15	−128.0 (3)	C11—N3—C15—C14	−2.6 (5)
N5—Ru1—N4—C16	−131.4 (3)	Ru1—N3—C15—C14	170.2 (3)
N1—Ru1—N4—C16	136.1 (3)	C13—C14—C15—N3	0.6 (6)
N3—Ru1—N4—C16	−38.3 (3)	C20—N4—C16—C17	−2.0 (5)
Br1—Ru1—N4—C16	49.7 (2)	Ru1—N4—C16—C17	170.4 (3)
N5—Ru1—N4—C20	40.5 (3)	N4—C16—C17—C18	0.0 (6)
N1—Ru1—N4—C20	−52.1 (3)	C16—C17—C18—C19	2.2 (7)
N3—Ru1—N4—C20	133.5 (3)	C17—C18—C19—C20	−2.3 (7)
Br1—Ru1—N4—C20	−138.4 (3)	C16—N4—C20—C19	1.9 (5)
N1—Ru1—N5—C22^i	−162.8 (3)	Ru1—N4—C20—C19	−170.3 (3)
N4—Ru1—N5—C22^i	105.9 (3)	C18—C19—C20—N4	0.3 (6)
N3—Ru1—N5—C22^i	17.5 (3)	C22^i—N5—C21—C22	0.3 (5)
N2—Ru1—N5—C22^i	−72.1 (3)	Ru1—N5—C21—C22	180.0 (2)
N1—Ru1—N5—C21	17.5 (3)	N5—C21—C22—N5^i	−0.3 (6)
N4—Ru1—N5—C21	−73.8 (3)

Symmetry code: (i) −x+1/2, −y+1/2, −z.