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Acta Cryst. (2003). E59, m605-m607  [ doi:10.1107/S1600536803015605 ]

Aquachloro(4-cyanobenzoato-[kappa]O)(1,10-phenanthroline-[kappa]2N,N')copper(II) monohydrate

Y.-L. Zhou, H.-Y. He, Y. Zhang and L.-G. Zhu

Abstract: The reaction of copper(II) chloride with 4-cyanobenzoic acid and 1,10-phenanthroline in a mixture of dimethylformamide and methanol gives the title complex, [CuCl(C8H4NO2)(C12H8N2)(H2O)]·H2O. The CuII ion is coordinated by one 1,10-phenanthroline, one water molecule, one Cl atom, and one 4-cyanobenzoate ligand. In the crystal structure, there are O-H...Cl hydrogen bonds and [pi]-[pi]-stacking interactions.

Online 24 July 2003


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