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Acta Cryst. (2003). E59, m739-m741  [ doi:10.1107/S1600536803017239 ]

Propane-1,2-diammonium hydrogenarsenate monohydrate

C. Lee and W. T. A. Harrison

Abstract: The title compound, [H3NCH2CH(NH3)CH3][HAsO4]·H2O, contains a network of doubly protonated propane-1,2-diammonium cations, hydrogenarsenate anions [dav(As-O) = 1.682  (1)  Å] and water molecules. Crystal symmetry generates a racemic mixture of the two enantiomers of the organic species. The crystal packing is controlled by N-H...O [dav(H...O) = 1.89  Å, [theta]av(N-H...O) = 167° and dav(N...O) = 2.760  (1)  Å] and O-H...O [dav(H...O) = 1.86  Å, [theta]av(O-H...O) = 175° and dav(O...O) = 2.712  (1)  Å] hydrogen bonds. It is isostructural with its hydrogenphosphate congener.

Online 15 August 2003


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