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Acta Cryst. (2003). E59, m809-m811  [ doi:10.1107/S1600536803018762 ]

Aqua(oxydiacetato-[kappa]3O,O',O'')(1,10-phenanthroline-[kappa]2N,N')cobalt(II) sesquihydrate

Z.-Y. Wu, Y.-H. Xue and D.-J. Xu

Abstract: The title compound, [Co(C4H4O5)(C12H8N2)H2O]·1.5H2O, consists of the octahedral complex and lattice water. The asymmetric unit contains two molecules of the complex, which form a hydrogen-bonded dimer. The overlapped arrangement and shorter separations of 3.532  (6) and 3.385  (12)  Å between neighboring parallel phenanthroline rings suggest the existence of [pi]-[pi]-stacking interactions.

Online 30 August 2003


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