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Acta Cryst. (2003). E59, o1395-o1397  [ doi:10.1107/S1600536803018075 ]

6a,14a-cis-6,6a,7,14a-Tetrahydrochromeno[4',3':3,4]pyrano[3,2-c]coumarin

R. Krishna, P. G. Aravindan, M. Yogavel, D. Velmurugan, S. Shanmuga Sundara Raj, H.-K. Fun, M. Shanmuga Sundaram and R. Raghunathan

Abstract: The title compound, C19H14O4, crystallizes with two molecules in the asymmetric unit. The dihydropyran rings adopt a half-chair conformation or a conformation intermediate between a sofa and half-chair. The inversion-related type A and B molecules and vice versa are linked by C-H...O hydrogen bonds, forming an infinite chain along the a axis. The molecular packing is stabilized by C-H...O interactions.


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