Acta Cryst. (2003). E59, m726-m728  [ doi:10.1107/S1600536803017422 ]

Bis(4-aminopyridine)silver(I) trifluoroacetate

H.-L. Zhu, Q.-F. Zeng, D.-S. Xia, X.-Y. Liu and D.-Q. Wang

Abstract: In the title mononuclear complex, [Ag(C₅H₆N₂)₂](CF₃O₂), the Ag atom is coordinated in an almost linear configuration by the pyridine N atoms of two 4-aminopyridine ligands. An O atom from the trifluoroacetate anion weakly ligates to the Ag atom to give a T-shaped environment. In the crystal structure, the two moieties are interconnected by N-HO hydrogen bonds and weak AgF interactions to form layers.

Online 15 August 2003

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