[HTML version][PDF version][CIF][3d view][Structure Factors][CIF check Report][Issue contents]  [Buy article online]

[Contents scheme]

Acta Cryst. (2003). E59, m774-m776  [ doi:10.1107/S1600536803017872 ]

trans-Bis(carbazol-3-ylethynyl)bis(tri-n-butylphosphine)platinum(II)

M. S. Khan, R. K. M. Al-Saadi, L. Male, P. R. Raithby and J. K. Bjernemose

Abstract: The title compound, [Pt(C12H27P)2(C14H8N)2], is a mononuclear PtII di-yne exhibiting [pi]-conjugation along the molecular backbone. It is used as a model species for rigid-rod platinum poly yne compounds of which it is a precursor. Such compounds are of interest due to the extended [pi]-conjugation through the hetero-aromatic linker unit in the backbone.

Online 23 August 2003


Copyright © International Union of Crystallography
IUCr Webmaster