Acta Cryst. (2003). E59, m939-m941  [ doi:10.1107/S1600536803019743 ]

Dichlorobis(tetrahydrofuran)(N,N'-di-tert-butylethane-1,2-diamine)vanadium(II)

A. C. Niedwieski, G. J. Leigh, T. Hasegawa and F. S. Nunes

Abstract: The title complex, [VCl₂(dtbeda)(thf)₂] (dtbeda is N,N'-di-tert-butylethane-1,2-diamine), was prepared from the reaction of [V₂Cl₃(thf)₆]₂[Zn₂Cl₆] with dtbeda in refluxing thf. The crystal structure of [VCl₂(dtbeda)(thf)₂] exhibits chlorides in trans positions in a distorted octahedral geometry around the vanadium site. The asymmetric unit consists of one-half of the complex, which is located on a twofold rotation axis in space group C2/c.

Online 24 September 2003

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