Acta Cryst. (2003). E59, m883-m885  [ doi:10.1107/S1600536803019391 ]

trans-Diaquabis(isoquinoline-1-carboxylato-²N,O)iron(II) dihydrate

Y. Muranishi and N. Okabe

Abstract: The title complex, [Fe(C₁₀H₆NO₂)₂(H₂O)₂]·2(H₂O), has a six-coordinate Fe atom at a center of symmetry, with two bidentate isoquinoline ligands and two water molecules in a trans configuration. The coordination bond length of the aqua O atom [2.180  (2)  Å] in the axial direction is longer than those of the carboxylato O atom and the ring N atom of the bidentate isoquinoline-1-carboxylate ligand in the equatorial plane [2.091  (2) and 2.153  (2)  Å, respectively].

Online 11 September 2003

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