Acta Cryst. (2003). E59, m897-m899  [ doi:10.1107/S160053680301972X ]

trans-Bis(isoquinoline-3-carboxylato-²N,O)bis(methanol-O)iron(II)

N. Okabe and Y. Muranishi

Abstract: The title complex, [Fe(C₁₀H₆NO₂)₂(CH₄O)₂], contains an Fe^II ion at a center of inversion. The Fe^II ion has a distorted octahedral coordination geometry, and is coordinated by two bidentate isoquinoline-3-carboxylate ligands through N and O atoms, and by two methanol O atoms. The two isoquinoline-3-carboxylate ligands lie in a trans position with respect to one another in the equatorial plane, and the two methanol ligands occupy the axial positions. The complex molecules are linked together by hydrogen bonds between the methanol ligands and the carboxylate groups.

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