trans-μ-(2,5-Dioctyl-1,4-phenyl­ene)­diethynyl-bis­[phenyl­bis­(triethyl­phosphine)­platinum(II)]

The title compound, [Pt₂(C₆H₅)₂(C₂₆H₃₆)(C₆H₁₅P)₄], is a dinuclear Pt^II di-yne compound exhibiting π-conjugation along the molecular backbone. It is used as a model species for rigid-rod platinum poly-yne compounds of which it is a precursor. Such compounds are of interest due to the extended π-conjugation through the aromatic linker unit in the backbone. In this structure, the mol­ecule lies on an inversion centre such that the asymmetric unit comprises half the formula unit.

Key indicators

• Single-crystal X-ray study
• T = 150 K
• Mean [sigma](C-C) = 0.018 Å
• R factor = 0.066
• wR factor = 0.171
• Data-to-parameter ratio = 18.4

checkCIF/PLATON results

No syntax errors found



Alert level A
PLAT027_ALERT_3_A _diffrn_reflns_theta_full too Low ..............      24.97 Deg.

Author Response: Data for this crystal were collected to a theta maximum of 25 degrees. This decision was taken as a consequence of the observed 'tailing off' in the crystal diffracting power at higher Bragg angles. The _diffrn_measured_fraction_theta_full fraction of 98% represents the maximum number of accessible reflections for a full hemisphere of data on our diffractometer.

PLAT220_ALERT_2_A Large Non-Solvent    C     Ueq(max)/Ueq(min) ...       5.34 Ratio

Author Response: While the sample chosen for X-ray analysis was the very best available (after copious recrystallisation attempts) it nevertheless was a very thin plate of average quality (minimum dimension = 0.08 mm). Hence, the data set was not as ideal as those which we routinely collect on our diffractometers. Nonetheless, solution and refinement of the crystal structure proceeded routinely, with the exception of the ADPs associated with some carbon atoms in the phosphines. Attempts were made to model disorder in regions where the electron density is somewhat smeared, but negligible progress was made in achieving a superior convergence than that presented herein.

PLAT222_ALERT_3_A Large Non-Solvent    H     Ueq(max)/Ueq(min) ...      10.00 Ratio

Author Response: See response to _vrf_PLAT220_I.

Alert level B
PLAT029_ALERT_3_B _diffrn_measured_fraction_theta_full Low .......       0.98

Alert level C
RINTA01_ALERT_3_C  The value of Rint is greater than 0.10
            Rint given   0.109
PLAT020_ALERT_3_C The value of Rint is greater than 0.10 .........       0.11
PLAT125_ALERT_4_C No _symmetry_space_group_name_Hall Given .......          ?
PLAT213_ALERT_2_C Atom C24     has ADP max/min Ratio .............       3.20 prolat
PLAT213_ALERT_2_C Atom C27     has ADP max/min Ratio .............       3.10 prolat
PLAT241_ALERT_2_C Check High   U(eq) as Compared to Neighbors ....        C24
PLAT242_ALERT_2_C Check Low    U(eq) as Compared to Neighbors ....         P1
PLAT242_ALERT_2_C Check Low    U(eq) as Compared to Neighbors ....         P2
PLAT242_ALERT_2_C Check Low    U(eq) as Compared to Neighbors ....        C28
PLAT250_ALERT_2_C Large U3/U1 ratio for average U(i,j) tensor ....       2.36
PLAT342_ALERT_3_C Low Bond Precision on C-C bonds (x 1000) Ang ...         18
PLAT360_ALERT_2_C Short  C(sp3)-C(sp3) Bond  C15    -   C16      =       1.42 Ang.
PLAT360_ALERT_2_C Short  C(sp3)-C(sp3) Bond  C17    -   C18      =       1.43 Ang.
PLAT371_ALERT_2_C Long   C(sp2)-C(sp1) Bond  C8     -   C9       =       1.45 Ang.
PLAT601_ALERT_2_C Structure Contains Solvent Accessible VOIDS of .      61.00 A   3  
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #          9
            PT1 -C7  -C8  -C9    -44.00 70.00   1.555   1.555   1.555   1.555
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #         10
            C7  -C8  -C9  -C11   154.00 35.00   1.555   1.555   1.555   1.555
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #         11
            C7  -C8  -C9  -C10   -28.00 35.00   1.555   1.555   1.555   1.555
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #         44
            C8  -C7  -PT1 -C4   -128.00 40.00   1.555   1.555   1.555   1.555
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #         45
            C8  -C7  -PT1 -P1   -172.00 43.00   1.555   1.555   1.555   1.555
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #         46
            C8  -C7  -PT1 -P2      7.00 43.00   1.555   1.555   1.555   1.555
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #         47
            C3  -C4  -PT1 -C7   -132.00 18.00   1.555   1.555   1.555   1.555
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #         48
            C5  -C4  -PT1 -C7     43.00 19.00   1.555   1.555   1.555   1.555
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #         59
            C22 -P1  -PT1 -P2   -179.00100.00   1.555   1.555   1.555   1.555
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #         60
            C24 -P1  -PT1 -P2    -62.00  4.00   1.555   1.555   1.555   1.555
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #         61
            C20 -P1  -PT1 -P2     58.00  4.00   1.555   1.555   1.555   1.555
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #         68
            C26 -P2  -PT1 -P1    123.00  4.00   1.555   1.555   1.555   1.555
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #         69
            C30 -P2  -PT1 -P1   -111.00  4.00   1.555   1.555   1.555   1.555
PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... #         70
            C28 -P2  -PT1 -P1      5.00  4.00   1.555   1.555   1.555   1.555

   3 ALERT level A = In general: serious problem
   1 ALERT level B = Potentially serious problem
  29 ALERT level C = Check and explain
   0 ALERT level G = General alerts; check

   0 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
  12 ALERT type 2 Indicator that the structure model may be wrong or deficient
   6 ALERT type 3 Indicator that the structure quality may be low
  15 ALERT type 4 Improvement, methodology, query or suggestion

---

Computing details

Data collection: COLLECT (Nonius, 1997-2000); cell refinement: HKL SCALEPACK (Otwinowski & Minor, 1997); data reduction: HKL DENZO (Otwinowski & Minor, 1997) and SCALEPACK; program(s) used to solve structure: DIRDIF99 (Beurskens et al., 1999); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEP-3 for Windows (Farrugia, 1997); software used to prepare material for publication: WinGX (Farrugia, 1999).

(I)

Crystal data

[Pt2(C6H5)2(C26H36)(C6H15P)4]	F(000) = 694
Mr = 1365.53	26112 integrated reflections used for unit cell measurement.
Triclinic, P1	Dx = 1.377 Mg m^−3
a = 8.8760 (4) Å	Mo Kα radiation, λ = 0.71073 Å
b = 13.7290 (9) Å	Cell parameters from 26112 reflections
c = 14.2320 (8) Å	θ = 2.9–25.0°
α = 81.892 (2)°	µ = 4.37 mm^−1
β = 74.610 (2)°	T = 150 K
γ = 82.388 (2)°	Plate, yellow
V = 1647.16 (16) Å^3	0.32 × 0.2 × 0.08 mm
Z = 1

Data collection

Bruker–Nonius KappaCCD diffractometer	4106 reflections with I > 2σ(I)
363 1° φ and 485 1° ω scans	Rint = 0.109
Absorption correction: multi-scan (SORTAV; Blessing, 1995)	θmax = 25.0°, θmin = 3.6°
Tmin = 0.291, Tmax = 0.705	h = −10→10
26112 measured reflections	k = −15→16
5684 independent reflections	l = −16→16

Refinement

Refinement on F^2	0 restraints
Least-squares matrix: full	H-atom parameters constrained
R[F^2 > 2σ(F^2)] = 0.066	w = 1/[σ^2(Fo^2) + (0.1002P)^2 + 1.5883P] where P = (Fo^2 + 2Fc^2)/3
wR(F^2) = 0.172	(Δ/σ)max = 0.001
S = 1.07	Δρmax = 2.29 e Å^−3
5684 reflections	Δρmin = −2.59 e Å^−3
309 parameters

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
C1	0.0543 (12)	0.1543 (9)	−0.0069 (9)	0.057 (3)
H1	0.0225	0.1221	−0.0523	0.068*
C2	0.1219 (12)	0.2416 (9)	−0.0369 (9)	0.056 (3)
H2	0.1356	0.2704	−0.1030	0.067*
C3	0.1704 (13)	0.2879 (9)	0.0297 (8)	0.055 (3)
H3	0.2165	0.3484	0.0079	0.066*
C4	0.1531 (11)	0.2477 (8)	0.1282 (7)	0.042 (2)
C5	0.0817 (11)	0.1586 (8)	0.1552 (8)	0.048 (3)
H5	0.0669	0.1288	0.2210	0.058*
C6	0.0327 (11)	0.1133 (8)	0.0898 (9)	0.050 (3)
H6	−0.0160	0.0537	0.1111	0.06*
C7	0.3325 (10)	0.3692 (8)	0.3141 (8)	0.045 (2)
C8	0.3838 (11)	0.4057 (7)	0.3709 (8)	0.043 (2)
C9	0.4420 (10)	0.4522 (8)	0.4379 (7)	0.041 (2)
C10	0.4548 (10)	0.5556 (8)	0.4217 (7)	0.046 (3)
H10	0.4247	0.5933	0.3671	0.055*
C11	0.4897 (10)	0.3972 (8)	0.5159 (7)	0.047 (3)
C12	0.4737 (11)	0.2866 (8)	0.5379 (8)	0.054 (3)
H12A	0.4975	0.2577	0.4750	0.007 (17)*
H12B	0.5529	0.2556	0.5734	0.06 (3)*
C13	0.3147 (12)	0.2612 (8)	0.5974 (9)	0.060 (3)
H13A	0.2360	0.2898	0.5606	0.072*
H13B	0.2889	0.2925	0.6591	0.072*
C14	0.3007 (14)	0.1505 (10)	0.6229 (10)	0.070 (4)
H14A	0.3933	0.1200	0.6467	0.084*
H14B	0.3053	0.1220	0.5620	0.084*
C15	0.1510 (18)	0.1206 (13)	0.7007 (12)	0.102 (5)
H15A	0.1613	0.0480	0.7176	0.122*
H15B	0.1425	0.1515	0.7610	0.122*
C16	0.0110 (19)	0.1491 (12)	0.6688 (14)	0.109 (6)
H16A	0.0104	0.1074	0.6176	0.131*
H16B	0.0134	0.2184	0.6380	0.131*
C17	−0.1437 (17)	0.1412 (13)	0.7498 (14)	0.108 (6)
H17A	−0.1514	0.0702	0.7736	0.13*
H17B	−0.1341	0.1740	0.8053	0.13*
C18	−0.2892 (18)	0.1806 (13)	0.7275 (14)	0.108 (6)
H18A	−0.3021	0.1442	0.6753	0.13*
H18B	−0.2782	0.2501	0.6989	0.13*
C19	−0.4380 (18)	0.1799 (14)	0.8061 (11)	0.102 (5)
H19A	−0.5255	0.2104	0.7787	0.153*
H19B	−0.4304	0.2172	0.8583	0.153*
H19C	−0.4561	0.1115	0.8332	0.153*
C20	0.4867 (12)	0.1252 (9)	0.0934 (9)	0.060 (3)
H20A	0.4045	0.0806	0.1257	0.072*
H20B	0.4602	0.1590	0.0328	0.072*
C21	0.6429 (13)	0.0623 (10)	0.0644 (10)	0.075 (4)
H21A	0.6347	0.0149	0.0210	0.113*
H21B	0.6694	0.0264	0.1234	0.113*
H21C	0.7252	0.1051	0.0302	0.113*
C22	0.6404 (14)	0.2897 (12)	0.1164 (12)	0.091 (5)
H22A	0.6564	0.3314	0.1635	0.109*
H22B	0.7368	0.2440	0.0980	0.109*
C23	0.616 (2)	0.3567 (15)	0.0235 (14)	0.118 (6)
H23A	0.7079	0.3933	−0.0055	0.177*
H23B	0.5223	0.4036	0.0414	0.177*
H23C	0.6019	0.3158	−0.0241	0.177*
C24	0.5417 (17)	0.1500 (13)	0.2798 (12)	0.100 (6)
H24A	0.6427	0.1102	0.2557	0.12*
H24B	0.5598	0.1974	0.3211	0.12*
C25	0.422 (2)	0.0810 (12)	0.3431 (11)	0.101 (6)
H25A	0.4612	0.0463	0.3981	0.151*
H25B	0.4051	0.0327	0.3032	0.151*
H25C	0.3218	0.1201	0.3684	0.151*
C26	−0.012 (2)	0.4928 (15)	0.3502 (14)	0.128 (9)
H26A	−0.1238	0.5189	0.3731	0.153*
H26B	0.0258	0.4636	0.4083	0.153*
C27	0.083 (3)	0.5755 (14)	0.297 (3)	0.218 (18)
H27A	0.0742	0.6260	0.3405	0.327*
H27B	0.0438	0.6049	0.2396	0.327*
H27C	0.1933	0.5495	0.2744	0.327*
C28	−0.1442 (13)	0.3161 (12)	0.3408 (10)	0.087 (5)
H28A	−0.2450	0.3564	0.3638	0.104*
H28B	−0.1607	0.2708	0.2969	0.104*
C29	−0.100 (2)	0.255 (2)	0.4284 (13)	0.174 (12)
H29A	−0.1840	0.2130	0.4622	0.26*
H29B	−0.0868	0.2990	0.4734	0.26*
H29C	−0.0020	0.2133	0.4063	0.26*
C30	−0.0829 (13)	0.4569 (9)	0.1711 (8)	0.060 (3)
H30A	−0.0091	0.5019	0.1275	0.072*
H30B	−0.0927	0.4048	0.1321	0.072*
C31	−0.2447 (12)	0.5161 (8)	0.2017 (9)	0.056 (3)
H31A	−0.2802	0.5441	0.1431	0.084*
H31B	−0.2365	0.5697	0.2383	0.084*
H31C	−0.3205	0.4722	0.2432	0.084*
P1	0.4790 (3)	0.2189 (2)	0.1752 (2)	0.0584 (8)
P2	0.0032 (3)	0.3987 (2)	0.2698 (2)	0.0526 (8)
Pt1	0.24274 (4)	0.31045 (3)	0.22167 (3)	0.0472 (2)

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
C1	0.037 (6)	0.068 (8)	0.074 (9)	0.007 (6)	−0.021 (5)	−0.037 (7)
C2	0.044 (6)	0.070 (9)	0.060 (7)	0.004 (6)	−0.021 (5)	−0.025 (6)
C3	0.054 (7)	0.056 (7)	0.058 (7)	−0.005 (5)	−0.014 (5)	−0.013 (6)
C4	0.031 (5)	0.045 (6)	0.054 (6)	0.005 (4)	−0.020 (4)	−0.015 (5)
C5	0.029 (5)	0.056 (7)	0.062 (7)	0.007 (5)	−0.014 (5)	−0.021 (6)
C6	0.030 (5)	0.046 (7)	0.076 (8)	0.000 (5)	−0.018 (5)	−0.008 (6)
C7	0.023 (5)	0.056 (7)	0.061 (7)	−0.001 (4)	−0.013 (5)	−0.019 (5)
C8	0.030 (5)	0.043 (6)	0.059 (6)	0.010 (4)	−0.017 (5)	−0.016 (5)
C9	0.025 (5)	0.057 (7)	0.042 (6)	0.002 (4)	−0.007 (4)	−0.020 (5)
C10	0.028 (5)	0.058 (8)	0.055 (6)	0.008 (5)	−0.014 (4)	−0.022 (5)
C11	0.021 (4)	0.064 (7)	0.059 (7)	0.007 (4)	−0.009 (4)	−0.033 (6)
C12	0.040 (6)	0.062 (8)	0.067 (7)	0.012 (5)	−0.022 (5)	−0.032 (6)
C13	0.045 (6)	0.063 (8)	0.068 (8)	0.002 (6)	−0.012 (5)	−0.006 (6)
C14	0.054 (7)	0.070 (9)	0.085 (9)	0.006 (6)	−0.011 (7)	−0.028 (7)
C15	0.076 (10)	0.107 (13)	0.120 (13)	0.016 (9)	−0.025 (10)	−0.026 (10)
C16	0.084 (11)	0.086 (11)	0.149 (16)	−0.009 (9)	−0.034 (11)	0.028 (11)
C17	0.065 (10)	0.097 (13)	0.158 (16)	0.000 (9)	−0.042 (10)	0.024 (11)
C18	0.070 (10)	0.104 (13)	0.141 (15)	0.001 (9)	−0.019 (10)	−0.001 (11)
C19	0.081 (11)	0.151 (16)	0.078 (10)	−0.007 (10)	−0.015 (8)	−0.037 (10)
C20	0.036 (6)	0.078 (8)	0.074 (8)	0.010 (5)	−0.018 (5)	−0.043 (6)
C21	0.037 (6)	0.089 (9)	0.106 (10)	0.015 (6)	−0.015 (6)	−0.054 (8)
C22	0.042 (7)	0.110 (12)	0.130 (13)	−0.007 (7)	−0.008 (8)	−0.071 (11)
C23	0.095 (13)	0.138 (17)	0.121 (15)	−0.032 (12)	−0.009 (11)	−0.026 (13)
C24	0.068 (9)	0.142 (14)	0.113 (12)	0.070 (10)	−0.065 (9)	−0.085 (11)
C25	0.107 (13)	0.103 (12)	0.082 (10)	0.052 (10)	−0.033 (9)	−0.014 (9)
C26	0.100 (12)	0.172 (19)	0.147 (15)	0.089 (13)	−0.086 (12)	−0.122 (14)
C27	0.17 (2)	0.071 (13)	0.50 (5)	0.004 (14)	−0.23 (3)	−0.05 (2)
C28	0.032 (6)	0.130 (13)	0.074 (9)	0.008 (7)	0.002 (6)	0.027 (9)
C29	0.084 (12)	0.27 (3)	0.096 (13)	0.075 (15)	0.014 (10)	0.069 (16)
C30	0.042 (6)	0.071 (8)	0.063 (7)	0.002 (6)	−0.010 (5)	−0.006 (6)
C31	0.041 (6)	0.052 (7)	0.073 (8)	0.008 (5)	−0.018 (5)	−0.007 (6)
P1	0.0335 (14)	0.072 (2)	0.081 (2)	0.0164 (13)	−0.0240 (14)	−0.0461 (17)
P2	0.0366 (14)	0.067 (2)	0.0575 (17)	0.0200 (13)	−0.0174 (12)	−0.0317 (15)
Pt1	0.0293 (2)	0.0591 (3)	0.0596 (3)	0.00917 (18)	−0.01801 (18)	−0.0279 (2)

Geometric parameters (Å, º)

C1—C2	1.375 (17)	C20—C21	1.523 (14)
C1—C6	1.385 (16)	C20—P1	1.836 (11)
C1—H1	0.95	C20—H20A	0.99
C2—C3	1.395 (15)	C20—H20B	0.99
C2—H2	0.95	C21—H21A	0.98
C3—C4	1.409 (15)	C21—H21B	0.98
C3—H3	0.95	C21—H21C	0.98
C4—C5	1.410 (15)	C22—C23	1.55 (2)
C4—Pt1	2.053 (10)	C22—P1	1.789 (14)
C5—C6	1.375 (14)	C22—H22A	0.99
C5—H5	0.95	C22—H22B	0.99
C6—H6	0.95	C23—H23A	0.98
C7—C8	1.216 (13)	C23—H23B	0.98
C7—Pt1	2.011 (10)	C23—H23C	0.98
C8—C9	1.451 (13)	C24—C25	1.54 (2)
C9—C11	1.382 (14)	C24—P1	1.823 (15)
C9—C10	1.421 (15)	C24—H24A	0.99
C10—C11^i	1.388 (13)	C24—H24B	0.99
C10—H10	0.95	C25—H25A	0.98
C11—C10^i	1.388 (13)	C25—H25B	0.98
C11—C12	1.525 (15)	C25—H25C	0.98
C12—C13	1.498 (15)	C26—C27	1.50 (3)
C12—H12A	0.99	C26—P2	1.811 (15)
C12—H12B	0.99	C26—H26A	0.99
C13—C14	1.525 (17)	C26—H26B	0.99
C13—H13A	0.99	C27—H27A	0.98
C13—H13B	0.99	C27—H27B	0.98
C14—C15	1.547 (19)	C27—H27C	0.98
C14—H14A	0.99	C28—C29	1.51 (2)
C14—H14B	0.99	C28—P2	1.840 (13)
C15—C16	1.42 (2)	C28—H28A	0.99
C15—H15A	0.99	C28—H28B	0.99
C15—H15B	0.99	C29—H29A	0.98
C16—C17	1.55 (2)	C29—H29B	0.98
C16—H16A	0.99	C29—H29C	0.98
C16—H16B	0.99	C30—C31	1.540 (14)
C17—C18	1.43 (2)	C30—P2	1.813 (11)
C17—H17A	0.99	C30—H30A	0.99
C17—H17B	0.99	C30—H30B	0.99
C18—C19	1.49 (2)	C31—H31A	0.98
C18—H18A	0.99	C31—H31B	0.98
C18—H18B	0.99	C31—H31C	0.98
C19—H19A	0.98	P1—Pt1	2.284 (3)
C19—H19B	0.98	P2—Pt1	2.289 (2)
C19—H19C	0.98
C2—C1—C6	119.8 (10)	C20—C21—H21B	109.5
C2—C1—H1	120.1	H21A—C21—H21B	109.5
C6—C1—H1	120.1	C20—C21—H21C	109.5
C1—C2—C3	119.9 (11)	H21A—C21—H21C	109.5
C1—C2—H2	120	H21B—C21—H21C	109.5
C3—C2—H2	120	C23—C22—P1	113.2 (11)
C2—C3—C4	122.0 (11)	C23—C22—H22A	108.9
C2—C3—H3	119	P1—C22—H22A	108.9
C4—C3—H3	119	C23—C22—H22B	108.9
C3—C4—C5	115.7 (9)	P1—C22—H22B	108.9
C3—C4—Pt1	121.2 (8)	H22A—C22—H22B	107.7
C5—C4—Pt1	122.9 (8)	C22—C23—H23A	109.5
C6—C5—C4	122.4 (10)	C22—C23—H23B	109.5
C6—C5—H5	118.8	H23A—C23—H23B	109.5
C4—C5—H5	118.8	C22—C23—H23C	109.5
C5—C6—C1	120.2 (11)	H23A—C23—H23C	109.5
C5—C6—H6	119.9	H23B—C23—H23C	109.5
C1—C6—H6	119.9	C25—C24—P1	113.1 (9)
C8—C7—Pt1	178.6 (8)	C25—C24—H24A	109
C7—C8—C9	178.2 (10)	P1—C24—H24A	109
C11—C9—C10	119.1 (9)	C25—C24—H24B	109
C11—C9—C8	121.2 (10)	P1—C24—H24B	109
C10—C9—C8	119.6 (9)	H24A—C24—H24B	107.8
C11^i—C10—C9	121.4 (10)	C24—C25—H25A	109.5
C11^i—C10—H10	119.3	C24—C25—H25B	109.5
C9—C10—H10	119.3	H25A—C25—H25B	109.5
C9—C11—C10^i	119.5 (10)	C24—C25—H25C	109.5
C9—C11—C12	120.9 (9)	H25A—C25—H25C	109.5
C10^i—C11—C12	119.5 (10)	H25B—C25—H25C	109.5
C13—C12—C11	114.3 (8)	C27—C26—P2	110.0 (16)
C13—C12—H12A	108.7	C27—C26—H26A	109.7
C11—C12—H12A	108.7	P2—C26—H26A	109.7
C13—C12—H12B	108.7	C27—C26—H26B	109.7
C11—C12—H12B	108.7	P2—C26—H26B	109.7
H12A—C12—H12B	107.6	H26A—C26—H26B	108.2
C12—C13—C14	114.3 (9)	C26—C27—H27A	109.5
C12—C13—H13A	108.7	C26—C27—H27B	109.5
C14—C13—H13A	108.7	H27A—C27—H27B	109.5
C12—C13—H13B	108.7	C26—C27—H27C	109.5
C14—C13—H13B	108.7	H27A—C27—H27C	109.5
H13A—C13—H13B	107.6	H27B—C27—H27C	109.5
C13—C14—C15	116.2 (11)	C29—C28—P2	114.2 (13)
C13—C14—H14A	108.2	C29—C28—H28A	108.7
C15—C14—H14A	108.2	P2—C28—H28A	108.7
C13—C14—H14B	108.2	C29—C28—H28B	108.7
C15—C14—H14B	108.2	P2—C28—H28B	108.7
H14A—C14—H14B	107.4	H28A—C28—H28B	107.6
C16—C15—C14	113.2 (14)	C28—C29—H29A	109.5
C16—C15—H15A	108.9	C28—C29—H29B	109.5
C14—C15—H15A	108.9	H29A—C29—H29B	109.5
C16—C15—H15B	108.9	C28—C29—H29C	109.5
C14—C15—H15B	108.9	H29A—C29—H29C	109.5
H15A—C15—H15B	107.7	H29B—C29—H29C	109.5
C15—C16—C17	115.4 (15)	C31—C30—P2	116.3 (8)
C15—C16—H16A	108.4	C31—C30—H30A	108.2
C17—C16—H16A	108.4	P2—C30—H30A	108.2
C15—C16—H16B	108.4	C31—C30—H30B	108.2
C17—C16—H16B	108.4	P2—C30—H30B	108.2
H16A—C16—H16B	107.5	H30A—C30—H30B	107.4
C18—C17—C16	119.3 (15)	C30—C31—H31A	109.5
C18—C17—H17A	107.5	C30—C31—H31B	109.5
C16—C17—H17A	107.5	H31A—C31—H31B	109.5
C18—C17—H17B	107.5	C30—C31—H31C	109.5
C16—C17—H17B	107.5	H31A—C31—H31C	109.5
H17A—C17—H17B	107	H31B—C31—H31C	109.5
C17—C18—C19	120.1 (16)	C22—P1—C24	102.7 (8)
C17—C18—H18A	107.3	C22—P1—C20	105.5 (6)
C19—C18—H18A	107.3	C24—P1—C20	104.6 (6)
C17—C18—H18B	107.3	C22—P1—Pt1	114.7 (5)
C19—C18—H18B	107.3	C24—P1—Pt1	112.2 (4)
H18A—C18—H18B	106.9	C20—P1—Pt1	115.8 (3)
C18—C19—H19A	109.5	C26—P2—C30	106.3 (7)
C18—C19—H19B	109.5	C26—P2—C28	103.3 (10)
H19A—C19—H19B	109.5	C30—P2—C28	102.6 (6)
C18—C19—H19C	109.5	C26—P2—Pt1	117.4 (5)
H19A—C19—H19C	109.5	C30—P2—Pt1	115.3 (4)
H19B—C19—H19C	109.5	C28—P2—Pt1	110.3 (5)
C21—C20—P1	115.9 (8)	C7—Pt1—C4	178.8 (4)
C21—C20—H20A	108.3	C7—Pt1—P1	88.0 (3)
P1—C20—H20A	108.3	C4—Pt1—P1	91.2 (3)
C21—C20—H20B	108.3	C7—Pt1—P2	92.6 (3)
P1—C20—H20B	108.3	C4—Pt1—P2	88.2 (3)
H20A—C20—H20B	107.4	P1—Pt1—P2	178.58 (11)
C20—C21—H21A	109.5
C6—C1—C2—C3	0.9 (15)	C27—C26—P2—C28	−171.1 (11)
C1—C2—C3—C4	0.3 (16)	C27—C26—P2—Pt1	67.2 (13)
C2—C3—C4—C5	−0.9 (14)	C31—C30—P2—C26	−48.5 (12)
C2—C3—C4—Pt1	174.5 (8)	C31—C30—P2—C28	59.6 (11)
C3—C4—C5—C6	0.4 (13)	C31—C30—P2—Pt1	179.6 (7)
Pt1—C4—C5—C6	−174.9 (7)	C29—C28—P2—C26	−71.0 (16)
C4—C5—C6—C1	0.7 (14)	C29—C28—P2—C30	178.7 (14)
C2—C1—C6—C5	−1.4 (15)	C29—C28—P2—Pt1	55.3 (16)
Pt1—C7—C8—C9	−44 (70)	C8—C7—Pt1—C4	−128 (40)
C7—C8—C9—C11	154 (35)	C8—C7—Pt1—P1	−172 (43)
C7—C8—C9—C10	−28 (35)	C8—C7—Pt1—P2	7 (43)
C11—C9—C10—C11^i	−1.7 (14)	C3—C4—Pt1—C7	−132 (18)
C8—C9—C10—C11^i	−179.8 (8)	C5—C4—Pt1—C7	43 (19)
C10—C9—C11—C10^i	1.6 (14)	C3—C4—Pt1—P1	−87.8 (8)
C8—C9—C11—C10^i	179.8 (8)	C5—C4—Pt1—P1	87.3 (7)
C10—C9—C11—C12	178.2 (8)	C3—C4—Pt1—P2	93.5 (8)
C8—C9—C11—C12	−3.7 (13)	C5—C4—Pt1—P2	−91.4 (7)
C9—C11—C12—C13	−83.8 (12)	C22—P1—Pt1—C7	−63.9 (7)
C10^i—C11—C12—C13	92.7 (11)	C24—P1—Pt1—C7	52.7 (7)
C11—C12—C13—C14	−177.6 (10)	C20—P1—Pt1—C7	172.7 (6)
C12—C13—C14—C15	168.4 (11)	C22—P1—Pt1—C4	116.9 (7)
C13—C14—C15—C16	66.0 (19)	C24—P1—Pt1—C4	−126.5 (7)
C14—C15—C16—C17	−167.7 (14)	C20—P1—Pt1—C4	−6.5 (6)
C15—C16—C17—C18	171.6 (17)	C22—P1—Pt1—P2	−179 (100)
C16—C17—C18—C19	−175.8 (17)	C24—P1—Pt1—P2	−62 (4)
C23—C22—P1—C24	−179.6 (11)	C20—P1—Pt1—P2	58 (4)
C23—C22—P1—C20	71.1 (12)	C26—P2—Pt1—C7	8.2 (9)
C23—C22—P1—Pt1	−57.7 (12)	C30—P2—Pt1—C7	134.7 (6)
C25—C24—P1—C22	−179.3 (10)	C28—P2—Pt1—C7	−109.7 (6)
C25—C24—P1—C20	−69.3 (11)	C26—P2—Pt1—C4	−172.6 (9)
C25—C24—P1—Pt1	57.0 (11)	C30—P2—Pt1—C4	−46.2 (6)
C21—C20—P1—C22	53.4 (12)	C28—P2—Pt1—C4	69.5 (6)
C21—C20—P1—C24	−54.5 (12)	C26—P2—Pt1—P1	123 (4)
C21—C20—P1—Pt1	−178.5 (9)	C30—P2—Pt1—P1	−111 (4)
C27—C26—P2—C30	−63.5 (12)	C28—P2—Pt1—P1	5 (4)

Symmetry code: (i) −x+1, −y+1, −z+1.