Acta Cryst. (2003). E59, m1083-m1085  [ doi:10.1107/S1600536803024462 ]

Aquabis(4-morpholinyldithiocarbamato)iron(III) trifluoromethanesulfonate

B. Wu, M. R. Taylor and L. L. Martin

Abstract: In the title compound, [Fe(C₅H₈NOS₂)₂(H₂O)]CF₃SO₃, the Fe atom has five-coordinate square-pyramidal stereochemistry, with the Fe atom 0.472  (1)  Å above the plane of four S atoms and a water molecule O atom at the apex. The cation has m (C_s) symmetry, with the crystallographic mirror plane passing through the Fe, O and N atoms. One O atom of the anion forms a strong hydrogen bond with the coordinated water molecule [OO = 2.642  (5)  Å]. This is the first report of a cationic [Fe(dithiocarbamate)₂L]ⁿ⁺ species.

Online 31 October 2003

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