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Acta Cryst. (2003). E59, m1059-m1061 [ doi:10.1107/S1600536803023699 ]
Abstract: The title compound, (C10H28N4)[AlF5(H2O)]2·2H2O, obtained solvothermally at 473 K and isostructural with the iron analogue, consists of isolated [AlF5(H2O)] octahedral anions and centrosymmetric tetraprotonated 1,4,8,11-tetraazacyclodecane (cyclamH44+) moieties connected by a network of N-H
X (X = O,F) hydrogen bonds. One water molecule participates in the aluminium coordination, whereas the second water molecule connects two neighbouring [AlF5(H2O)] octahedra via F1
H2WB-O2-H2WA
F3 bridges.
Online 23 October 2003
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