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Acta Cryst. (2003). E59, o1723-o1725  [ doi:10.1107/S1600536803022542 ]

2-Chloro-3,4-dimethoxybenzaldehyde 2,4-dinitrophenylhydrazone

S. Shan, W.-R. Chen, W.-X. Hu and D.-J. Xu

Abstract: Crystals of the title compound, C15H13ClN4O6, were obtained from a condensation reaction of 2-chloro-3,4-dimethoxybenzaldehyde and 2,4-dinitrophenylhydrazine. Within the dinitrophenyl group, the distances of 1.413  (3) and 1.405  (3)  Å for the C-C bonds close to the imino group are appreciably longer than the average distance of 1.372  (4)  Å for other aromatic C-C bonds in the same benzene ring. The benzene rings in the molecule are nearly coplanar, and the overlapped arrangement of benzene rings of neighboring molecules shows the existence of a [pi]-[pi] stacking interaction.

Online 15 October 2003


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