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Acta Cryst. (2003). E59, m1044-m1045  [ doi:10.1107/S1600536803022104 ]

{[mu]-9,10-Bis[(n-propylamino)methyl]anthracene-[kappa]2N:N'}bis{bis[6-chloro-2-(diphenylphosphino)pyridine-[kappa]P]copper(I)} diperchlorate

F.-B. Xu, H. Xu, X.-B. Leng, H.-B. Song, Q.-S. Li, R.-Y. Zou and Z.-Z. Zhang

Abstract: The title compound, [Cu2(C15H13ClP)4(C30H28N2)](ClO4)2, was synthesized by the reaction of 9,10-bis[(n-propylamino)methyl]anthracene and 6-chloro-2-(diphenylphosphino)pyridine with [Cu(CH3CN)4]ClO4. The Cu atoms adopt a trigonal-planar geometry and the cation is centrosymmetric. Three-layer [pi]-[pi] stacking interactions are observed between the anthracene and pyridyl rings.

Online 23 October 2003


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