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Acta Cryst. (2003). E59, m1192-m1193  [ doi:10.1107/S1600536803026709 ]

trans-Bis(3-aminopyridine)diaquabis(4-cyanobenzoato)cobalt(II) dihydrate

H.-Y. He and L.-G. Zhu

Abstract: The reaction of cobalt(II) acetate with 4-cyanobenzoic acid and 3-aminopyridine gave the title centrosymmetric complex, [Co(C8H4NO2)2(C5H6N2)2(H2O)2]·2H2O. The coordination geometry around the CoII ion is distorted octahedral, and the 4-cyanobenzoate and 3-aminopyridine ligands act in a monodentate fashion. The hydrogen bonds among the water molecules and cyano and amino groups ensure a two-dimensional hydrogen-bonding architecture.

Online 29 November 2003


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