Bis(μ-penta­fluoro­benzene­thiol­ato-κ2S:S)-trans-bis{(penta­fluoro­benzene­thiol­ato-κS)[(penta­fluoro­phenyl)­di­phenyl­phosphine-κP]­palladium(II)}

Villanueva, L.; Bernès, S.; Torrens, H.

doi:10.1107/S1600536803025558

Bis(μ-pentafluorobenzenethiolato-κ²S:S)-trans-bis{(pentafluorobenzenethiolato-κS)[(pentafluorophenyl)diphenylphosphine-κP]palladium(II)}

In the title compound, [Pd₂(C₆F₅S)₄(C₁₈H₁₀F₅P)₂], the molecule lies on an inversion center. The structure is characterized by a nearly planar [P,S-Pd(μ₂-S)₂Pd-S,P] moiety, with anti bridging thiolate ligands and terminal ligands in a mutually trans arrangement.

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Supporting information

	Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536803025558/om6189sup1.cif Contains datablocks global, I
	Structure factor file (CIF format) https://doi.org/10.1107/S1600536803025558/om6189Isup2.hkl Contains datablock I

CCDC reference: 227753

checkCIF report

Key indicators

Single-crystal X-ray study
T = 296 K
Mean (C-C) = 0.015 Å
R factor = 0.047
wR factor = 0.111
Data-to-parameter ratio = 12.6

checkCIF/PLATON results

No syntax errors found



Alert level B
PLAT220_ALERT_2_B Large Non-Solvent    C     Ueq(max)/Ueq(min) ...       4.39 Ratio
PLAT241_ALERT_2_B Check High   U(eq) as Compared to Neighbors ....        C27

Alert level C
PLAT213_ALERT_2_C Atom C22     has ADP max/min Ratio .............       3.10 prolat
PLAT213_ALERT_2_C Atom C23     has ADP max/min Ratio .............       3.10 prolat
PLAT241_ALERT_2_C Check High   U(eq) as Compared to Neighbors ....         S2
PLAT241_ALERT_2_C Check High   U(eq) as Compared to Neighbors ....        C22
PLAT241_ALERT_2_C Check High   U(eq) as Compared to Neighbors ....        C23
PLAT241_ALERT_2_C Check High   U(eq) as Compared to Neighbors ....        C28
PLAT242_ALERT_2_C Check Low    U(eq) as Compared to Neighbors ....         C9
PLAT242_ALERT_2_C Check Low    U(eq) as Compared to Neighbors ....        C15
PLAT242_ALERT_2_C Check Low    U(eq) as Compared to Neighbors ....        C17
PLAT242_ALERT_2_C Check Low    U(eq) as Compared to Neighbors ....        C19
PLAT242_ALERT_2_C Check Low    U(eq) as Compared to Neighbors ....        C25
PLAT342_ALERT_3_C Low Bond Precision on C-C bonds (x 1000) Ang ...         15
PLAT432_ALERT_2_C Short Inter X...Y Contact  F9     ..  C16      =       2.94 Ang.
PLAT731_ALERT_1_C Bond    Calc     1.39(3), Rep   1.394(13) ......       2.31 su-Rat
              C20  -C21     1.555   1.555

   0 ALERT level A = In general: serious problem
   2 ALERT level B = Potentially serious problem
  14 ALERT level C = Check and explain
   0 ALERT level G = General alerts; check

   1 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
  14 ALERT type 2 Indicator that the structure model may be wrong or deficient
   1 ALERT type 3 Indicator that the structure quality may be low
   0 ALERT type 4 Improvement, methodology, query or suggestion

Computing details top

Data collection: XSCANS (Fait, 1991); cell refinement: XSCANS; data reduction: XSCANS; program(s) used to solve structure: SHELXTL-Plus (Sheldrick, 1998); program(s) used to refine structure: SHELXTL-Plus; molecular graphics: SHELXTL-Plus; software used to prepare material for publication: SHELXTL-Plus.

Bis(µ-pentafluorobenzenethiolato-κ²S:S)-trans- bis{(pentafluorobenzenethiolato-κS)[(pentafluorophenyl)diphenylphosphine- κP]palladium(II)} top

Crystal data top

[Pd₂(C₆F₅S)₄(C₁₈H₁₀F₅P)₂]	F(000) = 3344
M_r = 1713.74	D_x = 1.804 Mg m⁻³
Monoclinic, C2/c	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -C 2yc	Cell parameters from 36 reflections
a = 26.807 (3) Å	θ = 2.8–12.0°
b = 14.3442 (18) Å	µ = 0.88 mm⁻¹
c = 20.3758 (15) Å	T = 296 K
β = 126.362 (6)°	Prism, red
V = 6309.4 (13) Å³	0.3 × 0.3 × 0.2 mm
Z = 4

Data collection top

Bruker P4 diffractometer	3530 reflections with I > 2σ(I)
Radiation source: fine-focus sealed tube, FN4	R_int = 0.037
Graphite monochromator	θ_max = 25.0°, θ_min = 1.8°
2θ/ω scans	h = −1→31
Absorption correction: ψ scan (Fait, 1991)	k = −1→17
T_min = 0.761, T_max = 0.841	l = −24→19
6476 measured reflections	3 standard reflections every 97 reflections
5561 independent reflections	intensity decay: 4.1%

Refinement top

Refinement on F²	Primary atom site location: heavy-atom method
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F² > 2σ(F²)] = 0.047	Hydrogen site location: inferred from neighbouring sites
wR(F²) = 0.111	H-atom parameters constrained
S = 1.00	w = 1/[σ²(F_o²) + (0.0437P)²] where P = (F_o² + 2F_c²)/3
5561 reflections	(Δ/σ)_max = 0.001
442 parameters	Δρ_max = 0.44 e Å⁻³
36 restraints	Δρ_min = −0.31 e Å⁻³

Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq
Pd1	0.304691 (17)	0.73813 (3)	0.10772 (2)	0.04837 (14)
P1	0.32023 (7)	0.63043 (12)	0.20065 (9)	0.0653 (4)
S1	0.21640 (6)	0.66039 (9)	−0.00180 (7)	0.0497 (3)
S2	0.38948 (7)	0.82052 (12)	0.21230 (8)	0.0697 (5)
C1	0.2414 (2)	0.5562 (4)	−0.0199 (3)	0.0542 (14)
C2	0.2160 (3)	0.4724 (4)	−0.0204 (4)	0.0673 (16)
C3	0.2287 (4)	0.3897 (5)	−0.0418 (5)	0.097 (2)
C4	0.2695 (5)	0.3898 (6)	−0.0606 (5)	0.107 (3)
C5	0.3003 (4)	0.4693 (6)	−0.0548 (4)	0.093 (2)
C6	0.2839 (3)	0.5522 (5)	−0.0377 (4)	0.0702 (16)
C7	0.4184 (2)	0.8848 (4)	0.1676 (3)	0.0553 (14)
C8	0.4405 (2)	0.8438 (5)	0.1280 (3)	0.0641 (15)
C9	0.4655 (3)	0.8951 (6)	0.0965 (4)	0.0707 (17)
C10	0.4695 (3)	0.9886 (6)	0.1045 (4)	0.0775 (19)
C11	0.4495 (3)	1.0319 (5)	0.1436 (4)	0.0710 (17)
C12	0.4240 (2)	0.9807 (4)	0.1742 (3)	0.0601 (15)
C13	0.3749 (3)	0.6613 (5)	0.3095 (3)	0.0701 (17)
C14	0.4296 (4)	0.6188 (6)	0.3666 (4)	0.093 (2)
C15	0.4663 (4)	0.6464 (7)	0.4483 (4)	0.106 (3)
C16	0.4483 (5)	0.7164 (8)	0.4728 (5)	0.114 (3)
C17	0.3947 (4)	0.7598 (7)	0.4192 (5)	0.102 (3)
C18	0.3591 (3)	0.7328 (6)	0.3382 (4)	0.084 (2)
C19	0.2503 (4)	0.6024 (6)	0.1933 (4)	0.101 (3)
C20	0.2526 (5)	0.5293 (8)	0.2410 (5)	0.159 (4)
H20A	0.2886	0.4945	0.2749	0.190*
C21	0.1994 (7)	0.5105 (11)	0.2359 (7)	0.211 (7)
H21A	0.1986	0.4624	0.2659	0.253*
C22	0.1486 (6)	0.5644 (14)	0.1858 (7)	0.241 (8)
H22A	0.1130	0.5504	0.1816	0.289*
C23	0.1460 (4)	0.6372 (13)	0.1413 (5)	0.221 (6)
H23A	0.1106	0.6737	0.1095	0.265*
C24	0.1990 (4)	0.6545 (9)	0.1455 (5)	0.152 (4)
H24A	0.1989	0.7028	0.1150	0.182*
C25	0.3505 (4)	0.5268 (5)	0.1851 (4)	0.083 (2)
C26	0.3322 (4)	0.4365 (7)	0.1827 (5)	0.129 (3)
H26A	0.3002	0.4254	0.1874	0.155*
C27	0.3603 (8)	0.3616 (11)	0.1735 (10)	0.192 (8)
H27A	0.3495	0.3010	0.1765	0.230*
C28	0.4031 (8)	0.3767 (12)	0.1602 (9)	0.187 (8)
H28A	0.4203	0.3262	0.1517	0.224*
C29	0.4213 (5)	0.4630 (9)	0.1588 (5)	0.144 (4)
H29A	0.4508	0.4726	0.1493	0.173*
C30	0.3950 (4)	0.5394 (6)	0.1722 (4)	0.105 (3)
H30A	0.4080	0.5995	0.1723	0.125*
F2	0.17796 (16)	0.4696 (2)	0.0018 (2)	0.0857 (11)
F3	0.1990 (2)	0.3119 (3)	−0.0469 (3)	0.147 (2)
F4	0.2832 (3)	0.3103 (3)	−0.0816 (3)	0.164 (2)
F5	0.3435 (2)	0.4686 (4)	−0.0678 (3)	0.1306 (17)
F6	0.31273 (17)	0.6297 (3)	−0.0347 (2)	0.0952 (12)
F8	0.43742 (18)	0.7498 (3)	0.1188 (3)	0.0973 (12)
F9	0.48525 (18)	0.8511 (4)	0.0581 (3)	0.1153 (15)
F10	0.49372 (18)	1.0374 (3)	0.0735 (3)	0.1165 (15)
F11	0.4531 (2)	1.1250 (3)	0.1521 (2)	0.1141 (14)
F12	0.40311 (16)	1.0270 (3)	0.2105 (2)	0.0834 (10)
F14	0.4507 (2)	0.5472 (4)	0.3478 (2)	0.1429 (19)
F15	0.5207 (3)	0.6010 (4)	0.5007 (3)	0.173 (3)
F16	0.4839 (3)	0.7408 (4)	0.5515 (3)	0.164 (2)
F17	0.3766 (3)	0.8311 (4)	0.4423 (3)	0.158 (2)
F18	0.3063 (2)	0.7793 (3)	0.2865 (3)	0.1163 (15)

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Pd1	0.0437 (2)	0.0583 (3)	0.0460 (2)	−0.0089 (2)	0.02812 (17)	−0.0056 (2)
P1	0.0654 (10)	0.0771 (11)	0.0495 (8)	−0.0236 (9)	0.0319 (8)	−0.0043 (8)
S1	0.0470 (7)	0.0552 (8)	0.0505 (7)	−0.0098 (6)	0.0309 (6)	−0.0061 (6)
S2	0.0602 (9)	0.0939 (12)	0.0503 (8)	−0.0305 (9)	0.0302 (7)	−0.0105 (8)
C1	0.051 (3)	0.061 (4)	0.042 (3)	−0.004 (3)	0.022 (3)	−0.007 (2)
C2	0.056 (4)	0.058 (4)	0.064 (4)	−0.002 (3)	0.023 (3)	−0.001 (3)
C3	0.098 (6)	0.063 (5)	0.086 (5)	−0.003 (5)	0.032 (4)	−0.006 (4)
C4	0.136 (8)	0.077 (6)	0.090 (5)	0.022 (6)	0.058 (6)	−0.009 (5)
C5	0.087 (5)	0.110 (7)	0.076 (5)	0.036 (5)	0.046 (4)	−0.002 (4)
C6	0.074 (4)	0.071 (4)	0.068 (4)	0.003 (4)	0.044 (4)	−0.005 (3)
C7	0.039 (3)	0.073 (4)	0.049 (3)	−0.008 (3)	0.024 (2)	−0.008 (3)
C8	0.050 (3)	0.067 (4)	0.066 (4)	−0.004 (3)	0.030 (3)	−0.009 (3)
C9	0.048 (3)	0.102 (6)	0.072 (4)	0.003 (4)	0.042 (3)	−0.002 (4)
C10	0.045 (4)	0.110 (6)	0.073 (4)	−0.003 (4)	0.033 (3)	0.012 (4)
C11	0.054 (4)	0.072 (5)	0.070 (4)	−0.004 (3)	0.027 (3)	0.010 (3)
C12	0.044 (3)	0.071 (4)	0.057 (3)	0.000 (3)	0.025 (3)	−0.003 (3)
C13	0.077 (4)	0.079 (5)	0.057 (4)	−0.028 (4)	0.042 (4)	−0.001 (3)
C14	0.105 (6)	0.082 (5)	0.071 (5)	−0.019 (5)	0.040 (5)	−0.009 (4)
C15	0.106 (7)	0.112 (7)	0.053 (4)	−0.033 (6)	0.021 (5)	0.004 (5)
C16	0.136 (8)	0.137 (9)	0.061 (5)	−0.072 (7)	0.054 (6)	−0.030 (6)
C17	0.122 (7)	0.125 (7)	0.080 (5)	−0.056 (6)	0.071 (5)	−0.043 (5)
C18	0.083 (5)	0.104 (6)	0.078 (5)	−0.034 (5)	0.055 (4)	−0.020 (4)
C19	0.091 (5)	0.169 (8)	0.054 (4)	−0.069 (5)	0.049 (4)	−0.027 (5)
C20	0.171 (9)	0.228 (11)	0.089 (6)	−0.121 (8)	0.084 (6)	−0.027 (6)
C21	0.201 (12)	0.342 (17)	0.100 (8)	−0.169 (13)	0.095 (8)	−0.029 (9)
C22	0.138 (9)	0.50 (2)	0.104 (9)	−0.162 (13)	0.084 (8)	−0.061 (12)
C23	0.093 (6)	0.51 (2)	0.082 (6)	−0.047 (10)	0.063 (5)	0.002 (9)
C24	0.084 (6)	0.312 (13)	0.080 (5)	−0.040 (8)	0.060 (5)	−0.019 (7)
C25	0.090 (5)	0.068 (5)	0.053 (4)	−0.007 (4)	0.021 (4)	−0.001 (3)
C26	0.135 (8)	0.079 (6)	0.106 (6)	−0.020 (6)	0.036 (6)	0.000 (5)
C27	0.23 (2)	0.074 (8)	0.152 (11)	−0.007 (12)	0.050 (12)	−0.015 (7)
C28	0.206 (18)	0.117 (13)	0.118 (9)	0.049 (13)	0.030 (11)	−0.016 (9)
C29	0.142 (9)	0.151 (10)	0.093 (6)	0.057 (9)	0.045 (6)	−0.004 (7)
C30	0.121 (7)	0.082 (6)	0.087 (5)	0.029 (5)	0.049 (5)	0.004 (4)
F2	0.068 (2)	0.071 (2)	0.097 (3)	−0.0094 (19)	0.037 (2)	0.013 (2)
F3	0.146 (4)	0.055 (3)	0.185 (5)	−0.015 (3)	0.068 (4)	−0.013 (3)
F4	0.200 (6)	0.098 (4)	0.169 (5)	0.044 (4)	0.096 (4)	−0.032 (3)
F5	0.138 (4)	0.154 (5)	0.132 (4)	0.051 (3)	0.098 (3)	0.000 (3)
F6	0.094 (3)	0.105 (3)	0.125 (3)	0.004 (2)	0.086 (3)	−0.002 (3)
F8	0.102 (3)	0.081 (3)	0.123 (3)	−0.001 (2)	0.074 (3)	−0.017 (2)
F9	0.101 (3)	0.164 (4)	0.122 (3)	0.017 (3)	0.088 (3)	−0.005 (3)
F10	0.096 (3)	0.152 (4)	0.125 (3)	−0.017 (3)	0.079 (3)	0.033 (3)
F11	0.134 (4)	0.074 (3)	0.126 (3)	−0.014 (3)	0.072 (3)	0.009 (2)
F12	0.084 (2)	0.086 (3)	0.087 (2)	0.001 (2)	0.054 (2)	−0.017 (2)
F14	0.136 (4)	0.140 (4)	0.072 (3)	0.021 (4)	0.018 (3)	−0.009 (3)
F15	0.151 (5)	0.168 (5)	0.075 (3)	−0.009 (4)	−0.002 (3)	−0.002 (3)
F16	0.198 (5)	0.190 (5)	0.068 (3)	−0.081 (4)	0.060 (3)	−0.049 (3)
F17	0.174 (5)	0.185 (6)	0.142 (4)	−0.051 (4)	0.109 (4)	−0.078 (4)
F18	0.108 (3)	0.141 (4)	0.114 (3)	−0.012 (3)	0.073 (3)	−0.031 (3)

Geometric parameters (Å, º) top

Pd1—P1	2.2826 (16)	C13—C18	1.366 (9)
Pd1—S2	2.3153 (14)	C14—F14	1.333 (8)
Pd1—S1	2.3586 (13)	C14—C15	1.397 (9)
Pd1—S1ⁱ	2.3768 (14)	C15—C16	1.334 (12)
P1—C25	1.810 (8)	C15—F15	1.358 (10)
P1—C19	1.834 (7)	C16—C17	1.335 (12)
P1—C13	1.846 (6)	C16—F16	1.338 (8)
S1—C1	1.765 (6)	C17—F17	1.331 (9)
S1—Pd1ⁱ	2.3768 (14)	C17—C18	1.385 (10)
S2—C7	1.765 (5)	C18—F18	1.338 (8)
C1—C2	1.380 (8)	C19—C24	1.346 (12)
C1—C6	1.386 (7)	C19—C20	1.406 (11)
C2—F2	1.338 (7)	C20—C21	1.394 (13)
C2—C3	1.376 (10)	C20—H20A	0.9300
C3—F3	1.338 (8)	C21—C22	1.36 (2)
C3—C4	1.355 (11)	C21—H21A	0.9300
C4—F4	1.344 (8)	C22—C23	1.36 (2)
C4—C5	1.372 (11)	C22—H22A	0.9300
C5—F5	1.330 (8)	C23—C24	1.392 (11)
C5—C6	1.382 (9)	C23—H23A	0.9300
C6—F6	1.334 (7)	C24—H24A	0.9300
C7—C12	1.381 (8)	C25—C30	1.375 (10)
C7—C8	1.385 (7)	C25—C26	1.377 (10)
C8—F8	1.357 (7)	C26—C27	1.387 (17)
C8—C9	1.385 (8)	C26—H26A	0.9300
C9—F9	1.334 (7)	C27—C28	1.34 (2)
C9—C10	1.347 (9)	C27—H27A	0.9300
C10—F10	1.341 (7)	C28—C29	1.337 (17)
C10—C11	1.348 (9)	C28—H28A	0.9300
C11—F11	1.342 (7)	C29—C30	1.414 (11)
C11—C12	1.379 (8)	C29—H29A	0.9300
C12—F12	1.338 (6)	C30—H30A	0.9300
C13—C14	1.362 (9)

P1—Pd1—S2	89.15 (5)	C14—C13—P1	127.2 (6)
P1—Pd1—S1	92.99 (5)	C18—C13—P1	117.9 (6)
S2—Pd1—S1	177.51 (6)	F14—C14—C13	121.7 (7)
P1—Pd1—S1ⁱ	174.80 (5)	F14—C14—C15	116.2 (8)
S2—Pd1—S1ⁱ	95.64 (5)	C13—C14—C15	122.1 (8)
S1—Pd1—S1ⁱ	82.26 (5)	C16—C15—F15	121.6 (8)
C25—P1—C19	110.4 (4)	C16—C15—C14	120.3 (9)
C25—P1—C13	106.8 (3)	F15—C15—C14	118.0 (9)
C19—P1—C13	101.3 (3)	C17—C16—C15	119.8 (8)
C25—P1—Pd1	106.9 (2)	C17—C16—F16	121.0 (10)
C19—P1—Pd1	113.9 (3)	C15—C16—F16	119.2 (11)
C13—P1—Pd1	117.3 (2)	F17—C17—C16	120.7 (8)
C1—S1—Pd1	107.78 (17)	F17—C17—C18	119.8 (10)
C1—S1—Pd1ⁱ	104.12 (18)	C16—C17—C18	119.5 (9)
Pd1—S1—Pd1ⁱ	97.74 (5)	F18—C18—C13	119.3 (6)
C7—S2—Pd1	106.48 (17)	F18—C18—C17	117.3 (8)
C2—C1—C6	116.2 (6)	C13—C18—C17	123.4 (8)
C2—C1—S1	119.4 (5)	C24—C19—C20	121.4 (8)
C6—C1—S1	124.3 (5)	C24—C19—P1	119.6 (7)
F2—C2—C3	117.6 (7)	C20—C19—P1	118.9 (8)
F2—C2—C1	119.8 (6)	C21—C20—C19	118.0 (11)
C3—C2—C1	122.6 (7)	C21—C20—H20A	121.0
F3—C3—C4	121.4 (9)	C19—C20—H20A	121.0
F3—C3—C2	119.7 (9)	C22—C21—C20	118.1 (12)
C4—C3—C2	118.8 (8)	C22—C21—H21A	121.0
F4—C4—C3	120.6 (10)	C20—C21—H21A	121.0
F4—C4—C5	117.9 (10)	C23—C22—C21	124.9 (12)
C3—C4—C5	121.5 (8)	C23—C22—H22A	117.6
F5—C5—C4	121.8 (8)	C21—C22—H22A	117.6
F5—C5—C6	120.0 (9)	C22—C23—C24	116.7 (13)
C4—C5—C6	118.1 (7)	C22—C23—H23A	121.7
F6—C6—C5	117.8 (6)	C24—C23—H23A	121.7
F6—C6—C1	119.7 (6)	C19—C24—C23	120.9 (11)
C5—C6—C1	122.4 (7)	C19—C24—H24A	119.6
C12—C7—C8	114.9 (5)	C23—C24—H24A	119.6
C12—C7—S2	121.7 (5)	C30—C25—C26	116.7 (9)
C8—C7—S2	123.3 (5)	C30—C25—P1	117.1 (6)
F8—C8—C7	119.4 (6)	C26—C25—P1	126.2 (8)
F8—C8—C9	118.1 (6)	C25—C26—C27	121.5 (12)
C7—C8—C9	122.5 (6)	C25—C26—H26A	119.3
F9—C9—C10	120.8 (7)	C27—C26—H26A	119.3
F9—C9—C8	119.4 (7)	C28—C27—C26	120.0 (18)
C10—C9—C8	119.8 (6)	C28—C27—H27A	120.0
F10—C10—C9	119.2 (7)	C26—C27—H27A	120.0
F10—C10—C11	120.8 (7)	C29—C28—C27	121 (2)
C9—C10—C11	120.1 (6)	C29—C28—H28A	119.3
F11—C11—C10	120.8 (7)	C27—C28—H28A	119.3
F11—C11—C12	119.2 (7)	C28—C29—C30	118.9 (14)
C10—C11—C12	120.0 (6)	C28—C29—H29A	120.6
F12—C12—C11	117.9 (6)	C30—C29—H29A	120.6
F12—C12—C7	119.4 (5)	C25—C30—C29	121.5 (10)
C11—C12—C7	122.7 (6)	C25—C30—H30A	119.2
C14—C13—C18	114.9 (7)	C29—C30—H30A	119.2

S2—Pd1—P1—C25	−107.5 (3)	C8—C7—C12—F12	179.1 (4)
S1—Pd1—P1—C25	73.8 (3)	S2—C7—C12—F12	−4.6 (7)
S2—Pd1—P1—C19	130.3 (3)	C8—C7—C12—C11	0.2 (8)
S1—Pd1—P1—C19	−48.4 (3)	S2—C7—C12—C11	176.4 (4)
S2—Pd1—P1—C13	12.3 (3)	C25—P1—C13—C14	4.0 (7)
S1—Pd1—P1—C13	−166.4 (3)	C19—P1—C13—C14	119.6 (7)
P1—Pd1—S1—C1	−70.3 (2)	Pd1—P1—C13—C14	−115.8 (6)
S1ⁱ—Pd1—S1—C1	107.6 (2)	C25—P1—C13—C18	−174.1 (5)
P1—Pd1—S1—Pd1ⁱ	−177.88 (6)	C19—P1—C13—C18	−58.5 (6)
S1ⁱ—Pd1—S1—Pd1ⁱ	0.0	Pd1—P1—C13—C18	66.1 (5)
P1—Pd1—S2—C7	154.5 (2)	C18—C13—C14—F14	179.1 (6)
S1ⁱ—Pd1—S2—C7	−23.5 (2)	P1—C13—C14—F14	1.0 (10)
Pd1—S1—C1—C2	125.7 (4)	C18—C13—C14—C15	0.5 (10)
Pd1ⁱ—S1—C1—C2	−131.3 (4)	P1—C13—C14—C15	−177.6 (6)
Pd1—S1—C1—C6	−57.4 (5)	F14—C14—C15—C16	−178.8 (7)
Pd1ⁱ—S1—C1—C6	45.7 (5)	C13—C14—C15—C16	−0.1 (12)
C6—C1—C2—F2	175.3 (5)	F14—C14—C15—F15	2.4 (11)
S1—C1—C2—F2	−7.5 (7)	C13—C14—C15—F15	−179.0 (7)
C6—C1—C2—C3	−3.6 (8)	F15—C15—C16—C17	179.4 (7)
S1—C1—C2—C3	173.5 (5)	C14—C15—C16—C17	0.6 (13)
F2—C2—C3—F3	6.0 (10)	F15—C15—C16—F16	−1.8 (13)
C1—C2—C3—F3	−175.0 (6)	C14—C15—C16—F16	179.4 (7)
F2—C2—C3—C4	−176.8 (7)	C15—C16—C17—F17	−178.6 (7)
C1—C2—C3—C4	2.2 (10)	F16—C16—C17—F17	2.7 (12)
F3—C3—C4—F4	−3.0 (12)	C15—C16—C17—C18	−1.4 (13)
C2—C3—C4—F4	179.8 (6)	F16—C16—C17—C18	179.8 (7)
F3—C3—C4—C5	−179.5 (7)	C14—C13—C18—F18	179.5 (6)
C2—C3—C4—C5	3.3 (12)	P1—C13—C18—F18	−2.2 (8)
F4—C4—C5—F5	−1.3 (12)	C14—C13—C18—C17	−1.4 (10)
C3—C4—C5—F5	175.3 (7)	P1—C13—C18—C17	176.9 (5)
F4—C4—C5—C6	176.5 (6)	F17—C17—C18—F18	−1.8 (10)
C3—C4—C5—C6	−7.0 (12)	C16—C17—C18—F18	−179.0 (7)
F5—C5—C6—F6	−0.1 (9)	F17—C17—C18—C13	179.1 (6)
C4—C5—C6—F6	−177.9 (6)	C16—C17—C18—C13	1.9 (11)
F5—C5—C6—C1	−176.8 (6)	C25—P1—C19—C24	−130.6 (7)
C4—C5—C6—C1	5.4 (10)	C13—P1—C19—C24	116.6 (7)
C2—C1—C6—F6	−176.8 (5)	Pd1—P1—C19—C24	−10.3 (8)
S1—C1—C6—F6	6.1 (8)	C25—P1—C19—C20	52.5 (7)
C2—C1—C6—C5	−0.2 (9)	C13—P1—C19—C20	−60.4 (7)
S1—C1—C6—C5	−177.2 (5)	Pd1—P1—C19—C20	172.7 (5)
Pd1—S2—C7—C12	122.6 (4)	C24—C19—C20—C21	1.7 (14)
Pd1—S2—C7—C8	−61.5 (5)	P1—C19—C20—C21	178.6 (8)
C12—C7—C8—F8	179.7 (5)	C19—C20—C21—C22	−0.6 (18)
S2—C7—C8—F8	3.5 (7)	C20—C21—C22—C23	−2 (2)
C12—C7—C8—C9	−0.9 (8)	C21—C22—C23—C24	3 (2)
S2—C7—C8—C9	−177.1 (4)	C20—C19—C24—C23	−0.5 (15)
F8—C8—C9—F9	0.3 (8)	P1—C19—C24—C23	−177.4 (8)
C7—C8—C9—F9	−179.1 (5)	C22—C23—C24—C19	−1.6 (18)
F8—C8—C9—C10	−179.9 (6)	C19—P1—C25—C30	167.1 (5)
C7—C8—C9—C10	0.7 (9)	C13—P1—C25—C30	−83.7 (6)
F9—C9—C10—F10	−0.1 (9)	Pd1—P1—C25—C30	42.6 (6)
C8—C9—C10—F10	−179.9 (5)	C19—P1—C25—C26	−11.1 (7)
F9—C9—C10—C11	−179.9 (5)	C13—P1—C25—C26	98.2 (6)
C8—C9—C10—C11	0.4 (10)	Pd1—P1—C25—C26	−135.5 (6)
F10—C10—C11—F11	0.3 (9)	C30—C25—C26—C27	4.4 (13)
C9—C10—C11—F11	−180.0 (6)	P1—C25—C26—C27	−177.5 (9)
F10—C10—C11—C12	179.2 (5)	C25—C26—C27—C28	−5 (2)
C9—C10—C11—C12	−1.1 (9)	C26—C27—C28—C29	3 (3)
F11—C11—C12—F12	0.8 (8)	C27—C28—C29—C30	0 (2)
C10—C11—C12—F12	−178.1 (5)	C26—C25—C30—C29	−1.2 (11)
F11—C11—C12—C7	179.7 (5)	P1—C25—C30—C29	−179.5 (6)
C10—C11—C12—C7	0.8 (9)	C28—C29—C30—C25	−1.1 (14)

Symmetry code: (i) −x+1/2, −y+3/2, −z.

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Bis(μ-penta­fluoro­benzene­thiol­ato-κ2S:S)-trans-bis{(penta­fluoro­benzene­thiol­ato-κS)[(penta­fluoro­phenyl)­di­phenyl­phosphine-κP]­palladium(II)}

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Bis(μ-pentafluorobenzenethiolato-κ²S:S)-trans-bis{(pentafluorobenzenethiolato-κS)[(pentafluorophenyl)diphenylphosphine-κP]palladium(II)}