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Acta Cryst. (2004). E60, m126-m128  [ doi:10.1107/S1600536803028976 ]

Dichloromethyl[1-(2-pyridyl)ethanone benzoylhydrazonato]tin(IV)

M. A. Affan, M. B. Shamsuddin, M. S. M. Yusof and B. M. Yamin

Abstract: The chelate Sn-O-C-N-N-C-C-N fragment, together with the substituent methyl C atom, in the title complex, [SnCl2(CH3)(C14H12N3O)], is planar, allowing the tridentate O,N,N-donor atoms and the methyl ligand C atom to occupy the equatorial positions in an octahedral environment. The geometry of the Sn atom is distorted octahedral, with a Cl-Sn-Cl axial bond angle of 172.02  (3)°.

Online 24 December 2003


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