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Acta Cryst. (2004). E60, m27-m29  [ doi:10.1107/S160053680302748X ]

Diaquabis(imidazole-[kappa]N)bis(nitrobenzoato-[kappa]O)nickel(II)

T.-G. Xu and D.-J. Xu

Abstract: The title complex, [Ni(C7H4NO4)2(C3H4N2)2(H2O)2], assumes an octahedral coordination geometry with the Ni atom located on an inversion centre. The overlapped arrangement and the separation of 3.535  (14)  Å suggest the existence of [pi]-[pi] stacking between parallel imidazole ligands. Both intramolecular and intermolecular hydrogen bonding occur between imidazole, coordinated water molecules and the carboxyl group.

Online 12 December 2003


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