(IUCr) Crystallography Journals Online

[Contents scheme]

Acta Cryst. (2004). E60, m166-m168 [ doi:10.1107/S1600536804000509 ]

Bis[-2-benz(oxa/thia)zolyl-2-phenolato-³N,O:O]bis{bis[2-benz(oxa/thia)zolyl-2-phenolato-²N,O]zinc(II)}

Y.-P. Tong, X.-M. Chen and S. W. Ng

Abstract: In the crystal structure of the title compound, [Zn₂(C₁₃H₄NO_1.67S_0.33)₄], the ring O atom in the benz(oxa/thia)zolyl-2-phenolate anions is disordered with respect to the S atom. The anions chelate to the Zn atom; the phenoxy O atom of two of them is also bridged to an adjacent molecule so that the geometry of the Zn atom in the centrosymmetric dimer is a trigonal bipyramid.

Online 17 January 2004

Bis[-2-benz(oxa/thia)zolyl-2-phenolato-3N,O:O]bis{bis[2-benz(oxa/thia)zolyl-2-phenolato-2N,O]zinc(II)}

Y.-P. Tong, X.-M. Chen and S. W. Ng

Bis[-2-benz(oxa/thia)zolyl-2-phenolato-³N,O:O]bis{bis[2-benz(oxa/thia)zolyl-2-phenolato-²N,O]zinc(II)}