Acta Cryst. (2004). E60, m169-m170  [ doi:10.1107/S1600536804000510 ]

catena-Poly[[aquamanganese(II)]-di--4-pyridylthioacetato-⁶O,O':N;N:O,O']

X.-M. Zhang, R.-Q. Fang, H.-S. Wu and S. W. Ng

Abstract: The Mn atom and the coordinated water molecule in the title compound, [Mn(C₇H₆NO₂S)₂(H₂O)]_n, lie on a twofold axis; the Mn atom is chelated by the carboxyl -CO₂ units and is also coordinated by the pyridyl N atoms of two adjacent anionic groups in a seven-coordinate trans-pentagonal bipyramidal geometry. The polymeric chain runs in a zigzag manner along the c axis, and neighboring chains are linked into a hydrogen-bonded layer structure.

Online 17 January 2004

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