Acta Cryst. (2004). E60, m193-m195  [ doi:10.1107/S1600536803028605 ]

The two-dimensional coordination polymer poly[[silver(I)-di--1,5-bis(phenylsulfanyl)pentane] tetrafluoroborate]

M. Du and X.-J. Zhao

Abstract: A two-dimensional silver(I) coordination polymer, {[Ag(L)₂]BF₄}_n, has been formed from AgBF₄ and 1,5-bis(phenylsulfanyl)pentane (L, C₁₇H₂₀S₂), in which each silver(I) center is coordinated by four S atoms from distinct ligands and displays a distorted tetrahedral geometry. Each ligand links two Ag^I atoms to form an infinite two-dimensional (4,4)-grid-like network. The BF₄^- ions are incorporated into the cavities of the coordination framework to complete and stabilize the structure.

Online 17 January 2004

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