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Acta Cryst. (2004). E60, m270-m272  [ doi:10.1107/S1600536804002454 ]

Aqua(2,2'-diamino-4,4-bi-1,3-thiazole-[kappa]2N,N')(oxydiacetato-[kappa]3O,O',O'')cobalt(II) monohydrate

Y. Luo, D.-J. Xu, Z.-Y. Wu, J.-Y. Wu and M. Y. Chiang

Abstract: In the title complex, [Co(C4H4O5)(C6H6N4S2)(H2O)]·H2O, the CoII atom has a distorted octahedral coordination geometry, formed by one tridentate oxydiacetate, one bidentate diaminobithiazole and one coordinated water molecule. The CoII atom lies on a crystallographic twofold axis, resulting in disorder of the oxydiacetate dianion and the coordinated water. In the crystal structure, parallel thiazole rings are separated by 3.343 (4) Å, allowing [pi]-[pi] stacking interactions to occur.

Online 7 February 2004


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