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Acta Cryst. (2004). E60, o439-o441  [ doi:10.1107/S1600536804004015 ]

2-(2-Pyridylamino)pyridinium nitrate monohydrate: two-dimensional supramolecular aggregation through hydrogen-bonding and [pi]-[pi] stacking interactions

M. Du and X.-J. Zhao

Abstract: In the crystal structure of the title compound, C10H10N3+·NO3-·H2O, (I), the asymmetric unit contains two crystallographically independent but similar subunits. The protonated C10H10N3+ cation adopts the normal trans-trans configuration and approximately planar geometry. Multiple hydrogen-bonding interactions expand the structure, resulting in a two-dimensional layered architecture, which is further stabilized by aromatic [pi]-[pi] stacking interactions between the protonated cations.

Online 28 February 2004


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