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Acta Cryst. (2004). E60, m458-m459 [ doi:10.1107/S1600536804006439 ]
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2-diphenylacetylene)(5-pentamethylcyclopentadienyl)triiridiumtungstenAbstract: The title compound, [WIr3(-C10H15)(3-2-C14H10)2(CO)7], is a mixed-metal cluster with a tetrahedral metal core geometry. One diphenylacetylene ligand is 3-2-coordinated to the triiridium face, while the other is 3-2-coordinated to a diiridiumtungsten face. The W atom is ligated by a pentamethylcyclopentadienyl ligand and a terminal carbonyl, and the Ir atoms are each ligated by two terminal carbonyls.
Online 27 March 2004
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