Acta Cryst. (2004). E60, m495-m497  [ doi:10.1107/S1600536804006774 ]

Aquabis(tetrahydrofuran)hexakis(trifluoroacetato)(₃-oxo)zinc(II)diiron(III)

M. M. Amini, M. Yadavi and S. W. Ng

Abstract: In the oxo-centered compound, [ZnFe₂O(O₂CCF₃)₆(C₄H₈O)₂(H₂O)], the central O atom is linked to three metal atoms, which are themselves each linked to four trifluoroacetate anions and are in a triangular configuration. Two of the metal atoms are each coordinated by a tetrahydrofuran molecule, whereas the third is coordinated by a water molecule. Two [ZnFe₂O(O₂CCF₃)₆(C₄H₈O)₂(H₂O)] units are linked by a pair of hydrogen bonds across a center of inversion to afford a hydrogen-bonded dimer. The compound is isostructural with the Cu^IIFe^III₂ analog.

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