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Acta Cryst. (2004). E60, m473-m476 [ doi:10.1107/S1600536804006877 ]
-2-aminopyridinato-bis[(2,2'-bipyridine)platinum(II)] dinitrate tetrahydrate as a head-to-tail isomerAbstract: In the title compound, [Pt2(C10H8N2)2(C5H5N2)2](NO3)2·4H2O, two 2-aminopyridinate ligands bridge two Pt atoms in a head-to-tail fashion, the Pt-Pt distance being 2.8724 (6) Å. The dimers form a one-dimensional stack based on
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stacking interactions between the bpy (2,2'-bipyridine) units, where the interplanar separations are estimated as 3.44 (2) and 3.45 (1) Å. No metal-metal interaction exists between the dimers.
Online 27 March 2004
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