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Acta Cryst. (2004). E60, m473-m476  [ doi:10.1107/S1600536804006877 ]

Di-[mu]-2-aminopyridinato-bis[(2,2'-bipyridine)platinum(II)] dinitrate tetrahydrate as a head-to-tail isomer

M. Mizota and K. Sakai

Abstract: In the title compound, [Pt2(C10H8N2)2(C5H5N2)2](NO3)2·4H2O, two 2-aminopyridinate ligands bridge two Pt atoms in a head-to-tail fashion, the Pt-Pt distance being 2.8724  (6)  Å. The dimers form a one-dimensional stack based on [pi]-[pi] stacking interactions between the bpy (2,2'-bipyridine) units, where the interplanar separations are estimated as 3.44  (2) and 3.45  (1)  Å. No metal-metal interaction exists between the dimers.

Online 27 March 2004


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