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The title compound, [Ni2(C24H24N2O2S)2]·CH2Cl2, is a centrosymmetric dimer. The Ni atoms are octahedrally coordinated by three O, one S and two N atoms. An intramolecular N—H...O hydrogen bond also connects the monomers.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536804004611/lh6176sup1.cif
Contains datablocks I, global

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S1600536804004611/lh6176Isup2.hkl
Contains datablock I

CCDC reference: 238639

Key indicators

  • Single-crystal X-ray study
  • T = 293 K
  • Mean [sigma](C-C) = 0.014 Å
  • Disorder in solvent or counterion
  • R factor = 0.127
  • wR factor = 0.333
  • Data-to-parameter ratio = 9.7

checkCIF/PLATON results

No syntax errors found



Alert level A THETM01_ALERT_3_A The value of sine(theta_max)/wavelength is less than 0.550 Calculated sin(theta_max)/wavelength = 0.5315
Author Response: The crystal was just weakly diffracting. Nevertheless, the data-to-parameter ratio is almost ten (9.7). ratio os
PLAT023_ALERT_3_A Resolution (too) Low [sin(th)/Lambda < 0.6].....      55.03 Deg.
Author Response: The crystal was just weakly diffracting. Nevertheless, the data-to-parameter ratio is almost ten (9.7).
PLAT027_ALERT_3_A _diffrn_reflns_theta_full (too) Low ............      55.03 Deg.
Author Response: The crystal was just weakly diffracting.Nevertheless, the data-to-parameter ratio is almost ten (9.7).
PLAT052_ALERT_1_A (Proper) Absorption Correction Method Missing ..          ?
PLAT057_ALERT_3_A Correction for Absorption Required   RT(exp) ...       1.48

Alert level C REFNR01_ALERT_3_C Ratio of reflections to parameters is < 10 for a centrosymmetric structure sine(theta)/lambda 0.5315 Proportion of unique data used 1.0000 Ratio reflections to parameters 9.7109 RFACG01_ALERT_3_C The value of the R factor is > 0.10 R factor given 0.127 RFACR01_ALERT_3_C The value of the weighted R factor is > 0.25 Weighted R factor given 0.333 PLAT082_ALERT_2_C High R1 Value .................................. 0.13 PLAT084_ALERT_2_C High R2 Value .................................. 0.33 PLAT088_ALERT_3_C Poor Data / Parameter Ratio .................... 9.71 PLAT221_ALERT_4_C Large Solvent/Anion Cl Ueq(max)/Ueq(min) ... 3.07 Ratio PLAT243_ALERT_4_C High Solvent U(eq) as Compared to Neighbors .... C1L PLAT302_ALERT_4_C Anion/Solvent Disorder ......................... 40.00 Perc. PLAT341_ALERT_3_C Low Bond Precision on C-C bonds (x 1000) Ang ... 14 PLAT432_ALERT_2_C Short Inter X...Y Contact Cl2 .. C94 .. 3.20 Ang. PLAT720_ALERT_4_C Number of Unusual/Non-Standard Label(s) ........ 2
Alert level G REFLT03_ALERT_1_G ALERT: Expected hkl max differ from CIF values From the CIF: _diffrn_reflns_theta_max 55.03 From the CIF: _reflns_number_total 2855 From the CIF: _diffrn_reflns_limit_ max hkl 25. 2. 22. From the CIF: _diffrn_reflns_limit_ min hkl -25. -8. 0. TEST1: Expected hkl limits for theta max Calculated maximum hkl 26. 8. 24. Calculated minimum hkl -26. -8. -24.
5 ALERT level A = In general: serious problem 0 ALERT level B = Potentially serious problem 12 ALERT level C = Check and explain 1 ALERT level G = General alerts; check 2 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 3 ALERT type 2 Indicator that the structure model may be wrong or deficient 9 ALERT type 3 Indicator that the structure quality may be low 4 ALERT type 4 Improvement, methodology, query or suggestion

Computing details top

Data collection: SDP (Enraf-Nonius, 1985); cell refinement: SDP; data reduction: SDP; program(s) used to solve structure: SHELXS97 (Sheldrick, 1990); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: XP in SHELXTL-Plus (Sheldrick, 1991); software used to prepare material for publication: SHELXL97 and PLATON (Spek, 1990).

(I) top
Crystal data top
[Ni2(C24H24N2O2S)2]·CH2Cl2F(000) = 2104
Mr = 1011.37Dx = 1.460 Mg m3
Monoclinic, C2/cCu Kα radiation, λ = 1.54180 Å
Hall symbol: -C 2ycCell parameters from 25 reflections
a = 25.380 (2) Åθ = 20–30°
b = 7.976 (1) ŵ = 3.33 mm1
c = 22.950 (2) ÅT = 293 K
β = 97.82 (1)°Block, green
V = 4602.6 (8) Å30.40 × 0.30 × 0.20 mm
Z = 4
Data collection top
Enraf-Nonius CAD-4
diffractometer
2268 reflections with I > 2σ(I)
Radiation source: fine-focus sealed tubeRint = 0.095
Graphite monochromatorθmax = 55.0°, θmin = 3.5°
ω scansh = 2525
Absorption correction: ψ scan
(North et al. 1968)
k = 82
Tmin = 0.327, Tmax = 0.518l = 022
3487 measured reflections3 standard reflections every 90 min
2855 independent reflections intensity decay: 2.3%
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.127Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.333H-atom parameters constrained
S = 1.41 w = 1/[σ2(Fo2) + (0.2P)2]
where P = (Fo2 + 2Fc2)/3
2855 reflections(Δ/σ)max < 0.001
294 parametersΔρmax = 1.66 e Å3
0 restraintsΔρmin = 1.20 e Å3
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/UeqOcc. (<1)
Ni0.27745 (5)0.21257 (15)0.56357 (6)0.0415 (7)
C10.3862 (4)0.1106 (11)0.6091 (4)0.055 (2)
H10.41030.03270.62720.066*
N10.3371 (3)0.0668 (8)0.6021 (3)0.0470 (17)
C30.3256 (4)0.1035 (10)0.6220 (5)0.062 (3)
H3A0.35810.16890.62560.075*
H3B0.31470.09570.66090.075*
C40.2851 (4)0.1916 (11)0.5841 (5)0.065 (3)
H4A0.28830.31020.59330.078*
H4B0.29200.17770.54390.078*
C50.2283 (3)0.1389 (10)0.5873 (4)0.053 (2)
H5A0.20460.21120.56180.063*
H5B0.22060.15550.62720.063*
N20.2165 (3)0.0392 (8)0.5701 (3)0.0460 (17)
H2N0.19860.03270.53300.055*
C70.1772 (3)0.1101 (11)0.6058 (4)0.050 (2)
H70.15150.02160.61090.060*
C80.2055 (4)0.1562 (11)0.6668 (4)0.058 (2)
H8A0.22390.05900.68500.069*
H8B0.17960.19280.69160.069*
S0.25252 (9)0.3225 (3)0.65985 (9)0.0516 (8)
O20.2156 (2)0.3605 (6)0.5233 (2)0.0440 (14)
O10.3274 (2)0.4031 (7)0.5562 (2)0.0478 (15)
C110.4081 (3)0.2664 (10)0.5920 (4)0.048 (2)
C120.4638 (4)0.2756 (13)0.6006 (6)0.075 (3)
H120.48340.18790.61940.090*
C130.4904 (4)0.4138 (14)0.5813 (6)0.086 (4)
H130.52730.41610.58520.103*
C140.4612 (4)0.5446 (13)0.5569 (5)0.069 (3)
H140.47870.63820.54480.083*
C150.4070 (4)0.5434 (11)0.5495 (4)0.059 (2)
H150.38860.63750.53380.071*
C160.3775 (3)0.3999 (10)0.5655 (4)0.046 (2)
C710.1676 (3)0.3746 (10)0.5413 (3)0.0440 (19)
C720.1468 (3)0.2560 (10)0.5768 (4)0.045 (2)
C730.0959 (4)0.2793 (11)0.5918 (4)0.057 (2)
H730.08250.20030.61570.069*
C740.0645 (4)0.4151 (12)0.5724 (5)0.070 (3)
H740.03040.42710.58250.084*
C750.0851 (4)0.5316 (11)0.5380 (4)0.061 (3)
H750.06480.62360.52390.074*
C760.1356 (3)0.5129 (10)0.5244 (4)0.050 (2)
H760.14940.59700.50280.059*
C910.3047 (4)0.2879 (10)0.7167 (4)0.051 (2)
C920.3499 (4)0.3843 (15)0.7162 (4)0.074 (3)
H920.35110.46460.68710.089*
C930.3927 (5)0.3620 (19)0.7584 (6)0.094 (4)
H930.42380.42200.75610.112*
C940.3905 (5)0.2487 (17)0.8055 (6)0.089 (4)
H940.41900.23800.83540.107*
C950.3454 (5)0.1557 (16)0.8060 (5)0.081 (3)
H950.34350.07790.83580.097*
C960.3046 (4)0.1751 (13)0.7646 (4)0.067 (3)
H960.27410.11180.76680.081*
C1L0.50000.815 (4)0.75000.23 (2)
H1LA0.53650.85010.74940.274*0.50
H1LB0.49960.74090.78350.274*0.50
Cl10.4802 (2)0.7053 (8)0.6881 (2)0.0865 (18)0.50
Cl20.4666 (7)0.9734 (19)0.7596 (5)0.265 (11)0.50
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Ni0.0494 (11)0.0370 (9)0.0424 (10)0.0003 (6)0.0219 (7)0.0022 (5)
C10.065 (6)0.043 (5)0.059 (6)0.007 (4)0.019 (4)0.000 (4)
N10.056 (5)0.046 (4)0.043 (4)0.002 (3)0.018 (3)0.005 (3)
C30.063 (6)0.039 (5)0.087 (7)0.002 (4)0.018 (5)0.009 (5)
C40.086 (7)0.038 (5)0.078 (7)0.003 (5)0.032 (5)0.007 (5)
C50.054 (5)0.043 (5)0.062 (6)0.000 (4)0.012 (4)0.011 (4)
N20.055 (4)0.039 (4)0.047 (4)0.001 (3)0.018 (3)0.008 (3)
C70.049 (5)0.057 (5)0.047 (5)0.008 (4)0.019 (4)0.003 (4)
C80.071 (6)0.056 (5)0.051 (6)0.008 (5)0.028 (4)0.005 (4)
S0.0642 (15)0.0502 (13)0.0439 (14)0.0003 (10)0.0200 (10)0.0002 (9)
O20.050 (3)0.043 (3)0.044 (3)0.001 (3)0.024 (3)0.005 (2)
O10.044 (4)0.048 (3)0.053 (4)0.001 (3)0.015 (3)0.007 (3)
C110.043 (5)0.043 (5)0.061 (6)0.003 (4)0.017 (4)0.005 (4)
C120.062 (7)0.063 (6)0.102 (9)0.006 (5)0.012 (6)0.008 (6)
C130.045 (6)0.076 (7)0.142 (11)0.005 (6)0.030 (6)0.012 (8)
C140.057 (6)0.062 (6)0.091 (8)0.021 (5)0.022 (5)0.005 (6)
C150.063 (6)0.044 (5)0.076 (7)0.001 (4)0.030 (5)0.011 (5)
C160.047 (5)0.049 (5)0.045 (5)0.005 (4)0.021 (4)0.014 (4)
C710.049 (5)0.047 (5)0.038 (5)0.004 (4)0.015 (4)0.008 (4)
C720.044 (5)0.045 (4)0.049 (5)0.006 (4)0.017 (4)0.004 (4)
C730.058 (6)0.058 (5)0.060 (6)0.009 (5)0.020 (4)0.006 (4)
C740.059 (6)0.061 (6)0.099 (8)0.005 (5)0.040 (6)0.014 (6)
C750.066 (6)0.047 (5)0.076 (7)0.008 (4)0.027 (5)0.001 (5)
C760.050 (5)0.053 (5)0.049 (5)0.007 (4)0.021 (4)0.004 (4)
C910.059 (6)0.057 (5)0.040 (5)0.007 (4)0.018 (4)0.008 (4)
C920.073 (7)0.095 (8)0.055 (6)0.029 (6)0.013 (5)0.000 (6)
C930.073 (7)0.129 (11)0.080 (9)0.020 (8)0.013 (6)0.009 (8)
C940.083 (9)0.114 (9)0.068 (8)0.016 (8)0.002 (6)0.005 (7)
C950.090 (8)0.092 (8)0.064 (7)0.004 (7)0.021 (6)0.005 (6)
C960.078 (7)0.073 (6)0.053 (6)0.005 (5)0.018 (5)0.012 (5)
C1L0.49 (7)0.14 (2)0.042 (13)0.0000.02 (2)0.000
Cl10.115 (5)0.102 (4)0.043 (3)0.016 (3)0.011 (3)0.018 (3)
Cl20.42 (3)0.278 (15)0.096 (8)0.227 (17)0.015 (10)0.028 (9)
Geometric parameters (Å, º) top
Ni—O12.000 (5)C13—C141.356 (14)
Ni—N12.015 (7)C13—H130.9300
Ni—O22.076 (5)C14—C151.362 (13)
Ni—N22.095 (6)C14—H140.9300
Ni—O2i2.107 (5)C15—C161.443 (12)
Ni—S2.536 (2)C15—H150.9300
C1—N11.283 (11)C71—C761.392 (12)
C1—C111.437 (12)C71—C721.399 (12)
C1—H10.9300C72—C731.394 (12)
N1—C31.475 (11)C73—C741.382 (13)
C3—C41.437 (14)C73—H730.9300
C3—H3A0.9700C74—C751.368 (14)
C3—H3B0.9700C74—H740.9300
C4—C51.513 (12)C75—C761.369 (12)
C4—H4A0.9700C75—H750.9300
C4—H4B0.9700C76—H760.9300
C5—N21.493 (10)C91—C921.382 (13)
C5—H5A0.9700C91—C961.421 (13)
C5—H5B0.9700C92—C931.365 (15)
N2—C71.486 (10)C92—H920.9300
N2—H2N0.9100C93—C941.417 (19)
C7—C721.500 (12)C93—H930.9300
C7—C81.530 (13)C94—C951.366 (17)
C7—H70.9800C94—H940.9300
C8—S1.806 (9)C95—C961.315 (14)
C8—H8A0.9700C95—H950.9300
C8—H8B0.9700C96—H960.9300
S—C911.750 (9)C1L—Cl2ii1.55 (2)
O2—C711.344 (9)C1L—Cl21.55 (2)
O2—Nii2.107 (5)C1L—Cl1ii1.686 (16)
O1—C161.262 (9)C1L—Cl11.686 (16)
C11—C121.403 (13)C1L—H1LA0.9699
C11—C161.407 (12)C1L—H1LB0.9701
C12—C131.395 (15)Cl2—Cl2ii1.81 (3)
C12—H120.9300
O1—Ni—N191.7 (2)Ni—O2—Nii96.2 (2)
O1—Ni—O288.8 (2)C16—O1—Ni127.3 (5)
N1—Ni—O2179.4 (3)C12—C11—C16120.5 (8)
O1—Ni—N2171.7 (2)C12—C11—C1115.3 (8)
N1—Ni—N296.0 (3)C16—C11—C1124.2 (8)
O2—Ni—N283.5 (2)C13—C12—C11121.2 (10)
O1—Ni—O2i89.7 (2)C13—C12—H12119.4
N1—Ni—O2i95.8 (2)C11—C12—H12119.4
O2—Ni—O2i83.8 (2)C14—C13—C12118.6 (9)
N2—Ni—O2i92.4 (2)C14—C13—H13120.7
O1—Ni—S92.68 (17)C12—C13—H13120.7
N1—Ni—S94.5 (2)C13—C14—C15122.1 (9)
O2—Ni—S85.89 (15)C13—C14—H14118.9
N2—Ni—S83.79 (19)C15—C14—H14118.9
O2i—Ni—S169.32 (16)C14—C15—C16121.6 (9)
N1—C1—C11127.3 (8)C14—C15—H15119.2
N1—C1—H1116.3C16—C15—H15119.2
C11—C1—H1116.3O1—C16—C11125.0 (7)
C1—N1—C3116.2 (7)O1—C16—C15119.2 (8)
C1—N1—Ni123.8 (6)C11—C16—C15115.9 (8)
C3—N1—Ni119.9 (6)O2—C71—C76120.0 (7)
C4—C3—N1114.7 (8)O2—C71—C72123.5 (7)
C4—C3—H3A108.6C76—C71—C72116.5 (7)
N1—C3—H3A108.6C73—C72—C71119.3 (8)
C4—C3—H3B108.6C73—C72—C7115.7 (7)
N1—C3—H3B108.6C71—C72—C7124.8 (7)
H3A—C3—H3B107.6C74—C73—C72122.6 (9)
C3—C4—C5116.3 (8)C74—C73—H73118.7
C3—C4—H4A108.2C72—C73—H73118.7
C5—C4—H4A108.2C75—C74—C73118.0 (9)
C3—C4—H4B108.2C75—C74—H74121.0
C5—C4—H4B108.2C73—C74—H74121.0
H4A—C4—H4B107.4C74—C75—C76120.1 (9)
N2—C5—C4114.1 (7)C74—C75—H75120.0
N2—C5—H5A108.7C76—C75—H75120.0
C4—C5—H5A108.7C75—C76—C71123.4 (8)
N2—C5—H5B108.7C75—C76—H76118.3
C4—C5—H5B108.7C71—C76—H76118.3
H5A—C5—H5B107.6C92—C91—C96116.6 (9)
C7—N2—C5109.9 (6)C92—C91—S116.8 (7)
C7—N2—Ni110.2 (5)C96—C91—S126.5 (8)
C5—N2—Ni121.6 (5)C93—C92—C91120.3 (11)
C7—N2—H2N104.5C93—C92—H92119.9
C5—N2—H2N104.5C91—C92—H92119.9
Ni—N2—H2N104.5C92—C93—C94120.9 (12)
N2—C7—C72113.3 (7)C92—C93—H93119.6
N2—C7—C8109.3 (7)C94—C93—H93119.6
C72—C7—C8111.6 (7)C95—C94—C93118.2 (11)
N2—C7—H7107.5C95—C94—H94120.9
C72—C7—H7107.5C93—C94—H94120.9
C8—C7—H7107.5C96—C95—C94120.6 (11)
C7—C8—S109.2 (6)C96—C95—H95119.7
C7—C8—H8A109.8C94—C95—H95119.7
S—C8—H8A109.8C95—C96—C91123.3 (10)
C7—C8—H8B109.8C95—C96—H96118.4
S—C8—H8B109.8C91—C96—H96118.4
H8A—C8—H8B108.3Cl2—C1L—Cl1115.9 (8)
C91—S—C8105.1 (4)Cl2—C1L—H1LA107.9
C91—S—Ni110.0 (3)Cl1—C1L—H1LA108.3
C8—S—Ni94.0 (3)Cl2—C1L—H1LB108.5
C71—O2—Ni125.0 (5)Cl1—C1L—H1LB108.5
C71—O2—Nii120.6 (5)H1LA—C1L—H1LB107.4
C11—C1—N1—C3178.1 (9)O2—Ni—O1—C16169.8 (6)
C11—C1—N1—Ni0.4 (13)O2i—Ni—O1—C1686.0 (6)
O1—Ni—N1—C14.5 (7)S—Ni—O1—C16104.4 (6)
N2—Ni—N1—C1178.4 (7)N1—C1—C11—C12174.9 (10)
O2i—Ni—N1—C185.3 (7)N1—C1—C11—C161.6 (15)
S—Ni—N1—C197.4 (7)C16—C11—C12—C132.2 (17)
O1—Ni—N1—C3177.9 (7)C1—C11—C12—C13174.4 (10)
N2—Ni—N1—C30.8 (7)C11—C12—C13—C143.7 (19)
O2i—Ni—N1—C392.3 (6)C12—C13—C14—C151.5 (19)
S—Ni—N1—C385.0 (6)C13—C14—C15—C162.1 (17)
C1—N1—C3—C4140.3 (9)Ni—O1—C16—C1110.8 (12)
Ni—N1—C3—C437.5 (10)Ni—O1—C16—C15170.9 (6)
N1—C3—C4—C576.1 (11)C12—C11—C16—O1179.7 (9)
C3—C4—C5—N261.9 (11)C1—C11—C16—O14.0 (14)
C4—C5—N2—C7145.7 (8)C12—C11—C16—C151.3 (13)
C4—C5—N2—Ni14.8 (10)C1—C11—C16—C15177.6 (8)
N1—Ni—N2—C7119.7 (5)C14—C15—C16—O1178.0 (9)
O2—Ni—N2—C760.8 (5)C14—C15—C16—C113.5 (13)
O2i—Ni—N2—C7144.2 (5)Ni—O2—C71—C76159.2 (6)
S—Ni—N2—C725.8 (5)Nii—O2—C71—C7676.2 (8)
N1—Ni—N2—C511.1 (6)Ni—O2—C71—C7220.9 (10)
O2—Ni—N2—C5168.4 (6)Nii—O2—C71—C72103.7 (8)
O2i—Ni—N2—C585.0 (6)O2—C71—C72—C73178.1 (8)
S—Ni—N2—C5105.0 (6)C76—C71—C72—C731.8 (12)
C5—N2—C7—C72156.5 (7)O2—C71—C72—C78.0 (13)
Ni—N2—C7—C7266.8 (8)C76—C71—C72—C7172.0 (8)
C5—N2—C7—C878.5 (8)N2—C7—C72—C73151.8 (7)
Ni—N2—C7—C858.3 (7)C8—C7—C72—C7384.4 (9)
N2—C7—C8—S64.8 (8)N2—C7—C72—C7134.2 (12)
C72—C7—C8—S61.2 (8)C8—C7—C72—C7189.6 (10)
C7—C8—S—C91147.9 (6)C71—C72—C73—C740.5 (13)
C7—C8—S—Ni36.0 (6)C7—C72—C73—C74174.9 (9)
O1—Ni—S—C9174.1 (4)C72—C73—C74—C751.0 (15)
N1—Ni—S—C9117.8 (4)C73—C74—C75—C760.9 (15)
O2—Ni—S—C91162.7 (4)C74—C75—C76—C713.5 (15)
N2—Ni—S—C91113.4 (4)O2—C71—C76—C75176.1 (8)
O2i—Ni—S—C91176.9 (9)C72—C71—C76—C753.9 (13)
O1—Ni—S—C8178.2 (3)C8—S—C91—C92171.0 (8)
N1—Ni—S—C889.9 (4)Ni—S—C91—C9270.9 (8)
O2—Ni—S—C889.6 (3)C8—S—C91—C9611.6 (9)
N2—Ni—S—C85.7 (4)Ni—S—C91—C96111.7 (8)
O2i—Ni—S—C875.5 (9)C96—C91—C92—C933.7 (16)
O1—Ni—O2—C71135.6 (6)S—C91—C92—C93178.6 (10)
N2—Ni—O2—C7141.4 (6)C91—C92—C93—C944.4 (19)
O2i—Ni—O2—C71134.6 (6)C92—C93—C94—C953 (2)
S—Ni—O2—C7142.8 (6)C93—C94—C95—C962.1 (19)
O1—Ni—O2—Nii89.8 (2)C94—C95—C96—C911.6 (19)
N2—Ni—O2—Nii93.2 (2)C92—C91—C96—C952.4 (16)
O2i—Ni—O2—Nii0.0S—C91—C96—C95179.8 (9)
S—Ni—O2—Nii177.39 (18)Cl1ii—C1L—Cl2—Cl2ii110.6 (10)
N1—Ni—O1—C169.8 (7)Cl1—C1L—Cl2—Cl2ii108.3 (11)
Symmetry codes: (i) x+1/2, y+1/2, z+1; (ii) x+1, y, z+3/2.
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
N2—H2N···O1i0.912.132.996 (9)160
Symmetry code: (i) x+1/2, y+1/2, z+1.
 

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