Acta Cryst. (2004). E60, m485-m486  [ doi:10.1107/S1600536804006440 ]

Bis(O,O'-di-p-tolyldithiophosphato-²S,S')nickel(II)

S.-S. Zhang, B. Yang, Y.-F. Wang, X.-M. Li, K. Jiao, M. B. Kassim and B. M. Yamin

Abstract: The title compound, [Ni(C₁₄H₁₄O₂PS₂)₂], consists of discrete molecules with the Ni atom chelated by both S atoms of the p-tolyldithiophosphate ligands in a bidentate manner in a four-coordinate environment. The molecule has inversion symmetry about the Ni atom, and the geometry is nearly perfect square planar, with S-Ni-S chelate bond angles of 89.12  (2)°.

Online 31 March 2004

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