Acta Cryst. (2004). E60, m403-m405  [ doi:10.1107/S1600536804005367 ]

Bis(2,2'-diamino-4,4'-bi-1,3-thiazole-²N,N')(isothiocyanato-N)(methanol)nickel(II) chloride

J.-G. Liu and D.-J. Xu

Abstract: The title compound, [Ni(NCS)(C₆H₆N₄S₂)(CH₄O)]Cl, consists of an Ni^II complex cation and a Cl^- anion. The Ni^II complex has an octahedral coordination, with the isothiocyanate and methanol ligands in cis positions. The diaminobithiazole ligands are each nearly planar, but the Ni^II atom is out of the planes of the thiazole rings, the deviations ranging from 0.113  (5) to 0.389  (4)  Å.

Online 20 March 2004

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