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Acta Cryst. (2004). E60, m687-m689 [ doi:10.1107/S1600536804009936 ]
![[mu]](/logos/entities/mu_rmgif.gif)
-phenylmethanethiolatobis[dicarbonyl(![[eta]](/logos/entities/eta_rmgif.gif)
5-cyclopentadienyl)molydenum(II)]Abstract: The reaction of bis[cyclopentadienyltricarbonylmolybdenum(I)] with dibenzyl trisulfide affords the dinuclear title compound, [MoII2(C5H5)2(C7H7S)2(CO)4], as one of the products. The two benzylthiolate anions function as bridges to the Mo atoms. The geometry of the Mo atom is described as pseudo-pentagonal bipyramidal if the cyclopentadienyl ring is assumed to occupy three sites.
Online 30 April 2004
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