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Acta Cryst. (2004). E60, m690-m692 [ doi:10.1107/S1600536804009948 ]
![[mu]](/logos/entities/mu_rmgif.gif)
-phenylmethanethiolato--sulfido-bis[carbonyl(![[eta]](/logos/entities/eta_rmgif.gif)
5-cyclopentadienyl)molybdenum(III)]Abstract: The reaction of bis[cyclopentadienyltricarbonylmolybdenum(I)] with dibenzyl trisulfide affords the title compound, [Mo2S(C5H5)2(C7H7S)2(CO)2], as one of the products. Three independent molecules exist in the asymmetric unit of the triclinic unit cell; one is related to another by a false inversion center and is related to the third by a false translation. In each dinuclear entity, each Mo atom is bonded to a cyclopentadienyl anion and a carbon monoxide molecule; the phenylmethanethiolate groups bridge a pair of Mo atoms, as does the sulfide atom.
Online 30 April 2004
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