Acta Cryst. (2004). E60, m566-m567  [ doi:10.1107/S1600536804008128 ]

Benzyltrimethylammonium tris(pyrimidine-2-thiolato-²N,S)nickelate(II)

L. Han, Y. Xu, B.-Y. Lou and M.-C. Hong

Abstract: The title compound, cis-[C₆H₅CH₂N(CH₃)₃][Ni(pymt)₃], (pymt = pyrimidine-2-thiolate, C₄H₃N₂S) consists of discrete cations and anions. The coordination geometry around nickel is highly distorted octahedral due to the presence of three four-membered N,S-chelate rings in a cis configuration. The Ni-S distances are in the range 2.4617  (5)-2.5290  (5)  Å and the Ni-N bond distances range from 2.0490  (14) to 2.0689  (14)  Å.

Online 17 April 2004

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