Acta Cryst. (2004). E60, m644-m646  [ doi:10.1107/S1600536804009389 ]

(Acetato-O)(diacetyl monoxime benzoylhydrazonato-³O,O',N)(quinoline-N)zinc(II) quinoline hemisolvate

S. Gao, L.-H. Huo, J.-W. Liu, C. Wang, J.-G. Zhao and S. W. Ng

Abstract: In the title complex, [Zn(C₁₁H₁₂N₃O₂)(C₂H₃O₂)(C₉H₇N)]·0.5C₉H₇N, the Zn^II atom is five-coordinate, bonded to one acetate O atom, one O atom and two N atoms from the tridentate hydrazone HL^- ligand (H₂L is diacetyl monoxime benzoylhydrazone), and one N atom from the quinoline molecule. The uncoordinated quinoline molecule is disordered and lies on a center of inversion. The presence of - stacking interactions between the coordinated quinoline ligands results in a chain structure along the a axis.

Online 24 April 2004

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