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Acta Cryst. (2004). E60, m551-m553 [ doi:10.1107/S1600536804007962 ]
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5-pentamethylcyclopentadienyl)iron(II)Abstract: In Cp*Fe(CO)2(n-C3H6Br), where Cp* = 5-C5(CH3)5, the Fe atom is coordinated by a pentamethylcyclopentadienyl ligand, two carbonyl ligands and a bromoalkyl chain in a pseudo-octahedral arrangement. The molecular geometry is similar to that reported for a related structure, with the alkyl chain in an all-trans conformation and a Fe-C(alkyl) bond length of 2.057 (3) Å. In the crystal structure, the molecules pack in layers.
Online 9 April 2004
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